Waterborne hybrid polyurethane coatings functionalized with (3-aminopropyl)triethoxysilane: Adhesion properties

Waterborne polyurethanes based on isophorone diisocyanate and two different soft segments, poly(1,4-butylene adipate) and poly(propylene glycol), were end-capped with (3-aminopropyl) triethoxysilane to impart them the ability to crosslink at room temperature. Polyurethanes were synthesized by means of acetone process and stabilized in aqueous medium using dimethylolpropionic acid (DMTA) as internal emulsifier. C-13 NMR experiments confirmed the insertion of the alkoxysilane. The adhesion properties of the room temperature cured films as a function of alkoxysilane concentration were evaluated. The optimum film formation time and adhesion temperatures were established using the design of experiments (DOE) methodology. The Lap Shear adhesion increased as a function of the alkoxysilane content up to a point, 9.7 wt.% of alkoxysilane, where the adhesion capacity disappeared totally due to the rigidity of the material. Furthermore, both polyester and polyether based systems presented an optimum window, between 5 and 15 wt.% of alkoxysilane, where the synthesized systems promoted good adhesion at high temperatures above 200 degrees C for more than 24h. (C) 2013 Elsevier B.V. All rights reserved.