Design rules for donors in bulk-heterojunction solar cells -: Towards 10 % energy-conversion efficiency

被引：4587
作者：
Scharber, MC
Wühlbacher, D
Koppe, M
Denk, P
Waldauf, C
Heeger, AJ
Brabec, CL
机构：
[1] Konarka Austria, A-4040 Linz, Austria
[2] Univ Calif Santa Barbara, Dept Mat Sci, Santa Barbara, CA 93106 USA
来源：
ADVANCED MATERIALS | 2006年 / 18卷 / 06期
基金：
美国国家科学基金会;
关键词：
D O I：
10.1002/adma.200501717
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
For bulk-heterojunction photovoltaic cells fabricated from conjugated polymers and a fullerene derivative, the relation between the open-circuit voltage (V-oc) and the oxidation potential for different conjugated polymers is studied. A linear relation between V-oc and the oxidation potential is found (see figure). Based on this relation, the energy-conversion efficiency of a bulk-heterojunction solar cell is derived as a function of the bandgap and the energy levels of the conjugated polymer.
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收藏
页码：789 / +
页数：7
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