Three biofilters were developed to treat high-temperature (50 degrees C) gaseous benzene, hexane, and toluene. The performance of the bioflIters was investigated; the parameters included removal efficiencies, kinetic analysis, biomass accumulation, pressure drops, and leachate TOC content. Results showed that the removal efficiency of toluene was the highest (more than 90%), followed by benzene (more than 70%) and hexane (more than 50%). The mass distribution coefficients (K-m) of benzene, hexane, and toluene were 4.99, 3.50, and 6.36, respectively. And the yield coefficients (Y) were 0.91, 1.29, and 1.50 g dry biomass/g removed VOC for benzene, hexane, and toluene, respectively. A faster biomass accumulation resulted in lower flooding velocity of the biofilter treating toluene (210 m/h) than that of the biofilter treating hexane (257 m/h). The leachate from the bialter treating toluene presented the highest TOC contents. Mass balance was similar among the three biofilters, suggesting that more than half of the removed VOCs were converted to CO2 and about 40% were converted to biomass. (C) 2015 Elsevier B.V. All rights reserved.