Organoboron compounds as mild nucleophiles in Lewis acid- and transition metal-catalyzed C-C bond-forming reactions

被引：13
作者：
Batey, RA [1 ]
Quach, TD [1 ]
Shen, M [1 ]
Thadani, AN [1 ]
Smil, DV [1 ]
Li, SW [1 ]
MacKay, DB [1 ]
机构：
[1] Univ Toronto, Dept Chem, Toronto, ON M5S 3H6, Canada
来源：
PURE AND APPLIED CHEMISTRY | 2002年 / 74卷 / 01期
关键词：
D O I：
10.1351/pac200274010043
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The use of air- and water-stable organoboron compounds for C-C bond-forming reactions are reported. These studies include the Lewis acid-promoted additions of boronic esters to N-acyliminium ions and allyl and crotyltrifluoroborate salts to aldehydes. Aryl and alkenyltifluoroborate salts will add to aldehydes under the influence of rhodium catalysis or in the presence of zinc metal. These salts also participate in palladium-catalyzed Suzuki-Miyaura and other cross-coupling reactions. Finally, a new type of N-heterocyclic carbene ligand is reported and used for Pd-catalyzed Suzuki-Miyaura couplings.
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页码：43 / 55
页数：13
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