Foldamers: They're Not Just for Biomedical Applications Anymore

被引：47

作者：

Prabhakaran, Panchami ^{[2
]}

Priya, Gowri ^{[1
]}

Sanjayan, Gangadhar J. ^{[1
]}

机构：

[1] Natl Chem Lab CSIR, Div Organ Chem, Pune 411008, Maharashtra, India

[2] Univ Leeds, Sch Chem, Leeds LS2 9JT, W Yorkshire, England

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2012年 / 51卷 / 17期

关键词：

foldamers; foldaxanes; molecular shuttles; nanotechnology; OLIGOMERS; HELIX;

D O I：

10.1002/anie.201107521

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new door is open! Foldamers have been successfully utilized for the development of a molecular device. Termed foldaxanes by analogy with rotaxanes, these structures are formed through a multitude of noncovalent interactions between double-helical foldamers and rod-shaped guest molecules. The foldaxanes move in a screw-type motion and open up yet another promising application of foldamers in materials science. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：4006 / 4008

页数：3

共 20 条

[1] A Self-Assembled Foldamer Capsule: Combining Single and Double Helical Segments in One Aromatic Amide Sequence [J].

Bao, Chunyan ;

Gan, Quan ;

Kauffmann, Brice ;

Jiang, Hua ;

Huc, Ivan .

CHEMISTRY-A EUROPEAN JOURNAL, 2009, 15 (43) :11530-11536

[2] Toward optomechanics: Maximizing the photodeformation of individual molecules [J].

Bleger, David ;

Yu, Zhilin ;

Hecht, Stefan .

CHEMICAL COMMUNICATIONS, 2011, 47 (45) :12260-12266

[3]

Ferrand Y., 2011, ANGEW CHEM, V123, P7714

[4] Template-Induced Screw Motions within an Aromatic Amide Foldamer Double Helix [J].

Ferrand, Yann ;

Gan, Quan ;

Kauffmann, Brice ;

Jiang, Hua ;

Huc, Ivan .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 50 (33) :7572-7575

[5] Helix-Rod Host-Guest Complexes with Shuttling Rates Much Faster than Disassembly [J].

Gan, Quan ;

Ferrand, Yann ;

Bao, Chunyan ;

Kauffmann, Brice ;

Grelard, Axelle ;

Jiang, Hua ;

Huc, Ivan .

SCIENCE, 2011, 331 (6021) :1172-1175

[6] Foldamers: A manifesto [J].

Gellman, SH .

ACCOUNTS OF CHEMICAL RESEARCH, 1998, 31 (04) :173-180

[7]

Hecht S., 2007, Foldamers: Structure, Properties and Applica tions

[8] Foldamers with Heterogeneous Backbones [J].

Horne, W. Seth ;

Gellman, Samuel H. .

ACCOUNTS OF CHEMICAL RESEARCH, 2008, 41 (10) :1399-1408

[9] Peptidic foldamers: ramping up diversity [J].

Martinek, Tamas A. ;

Fueloep, Ferenc .

CHEMICAL SOCIETY REVIEWS, 2012, 41 (02) :687-702

[10] The size-selective synthesis of folded oligomers by dynamic templation [J].

Nishinaga, T ;

Tanatani, A ;

Oh, KC ;

Moore, JS .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (21) :5934-5935

← 1 2 →