Single crystals of Metal-Organic Framework Ulm-4 grown selectively on a micro-structured plasma polymer coating

被引:1
作者
Schaller, Andreas [1 ]
Ullrich, Aladin [2 ]
Volkmer, Dirk [1 ]
机构
[1] Univ Augsburg, Chair Solid State & Mat Chem, Univ Str 1, D-86156 Augsburg, Germany
[2] Univ Augsburg, Chair Expt Phys 2, Univ Str 1, D-86156 Augsburg, Germany
关键词
Plasma enhanced chemical vapor deposition; Plasma polymer; Micro-structure; Metal-organic framework; SELF-ASSEMBLED MONOLAYERS; THIN-FILMS; STABILITY; NUCLEATION;
D O I
10.1016/j.tsf.2019.05.050
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
A multilayer plasma polymer coating was deposited on small glass discs and afterwards treated with ultra violet radiation through a patterned mask to generate a micro-structured substrate with an alternating hydrophilic/ hydrophobic surface. The substrate was then immersed in a mother liqueur of the porous, functional material Metal-Organic Framework Ulm-4 (MFU-4) to preferentially grow crystals on the hydrophilic areas of the film. X-ray diffraction and electron microscope analysis showed the formation of MFU-4 single crystals.
引用
收藏
页码:36 / 41
页数:6
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