Electrochemical sensor for detection of hydrazine based on Au@Pd core-shell nanoparticles supported on amino-functionalized TiO2 nanotubes

被引:50
作者
Chen, Xianlan [1 ,2 ,3 ]
Liu, Wei [1 ]
Tang, Lele [2 ]
Wang, Jian [1 ]
Pan, Haibo [2 ,3 ]
Du, Min [3 ]
机构
[1] Honghe Univ, Sch Sci, Mengzi 661100, Yunnan, Peoples R China
[2] Fuzhou Univ, Coll Chem & Chem Engn, Fuzhou 350108, Fujian, Peoples R China
[3] Fuzhou Univ, Fujian Key Lab Med Instrument & Pharmaceut Techno, Fuzhou 350002, Fujian, Peoples R China
来源
MATERIALS SCIENCE & ENGINEERING C-MATERIALS FOR BIOLOGICAL APPLICATIONS | 2014年 / 34卷
基金
美国国家科学基金会;
关键词
Hybrid nanostructures; Amino-functionalized TiO2 nanotubes; Flower-shaped Au@Pd nanostructures; Electrocatalytic activity; Hydrazine; SELF-ASSEMBLED MONOLAYERS; HYDROGEN-PRODUCTION; ELECTROCATALYTIC OXIDATION; GOLD NANOPARTICLES; CARBON NANOTUBES; OXYGEN REDUCTION; VISIBLE-LIGHT; WATER; ELECTRODE; 3-AMINOPROPYLTRIMETHOXYSILANE;
D O I
10.1016/j.msec.2013.09.016
中图分类号
TB3 [工程材料学]; R318.08 [生物材料学];
学科分类号
0805 ; 080501 ; 080502 ;
摘要
In this paper, we reported a simple strategy for synthesizing well-defined TiO2NTs-Au@Pd hybrid nanostructures with prior TiO2 nanotube functionalization (F-TiO2NTs). TiO2NTs with larger surface area (BET surface area is 184.9 m(2) g(-1)) were synthesized by hydrothermal method, and the NTs are anatase phase with a range of 2-3 mu m in length and 30-50 nm in diameter after calcined at 400 degrees C for 3 h. 3-Aminopropyl-trimethoxysilane (APTMS) as a coupling agent was reacted with the surface hydroxyl groups as anchoring sites for flower-shaped bimetallic Au@Pd nanostructures, self-assembling amine functionality on the surface of TiO2NTs. Note that two faces at the interface between F-TiO2NTs with (004) plane and Au@Pd nanostructures with (111) one of cubic Au and Pd nanoparticles are compatible, benefiting to the charge transfer between two components due to their crystalline coordination. The results showed that as-prepared F-TiO2NTs-Au@Pd hybrid nanostructures modified glassy carbon electrode (GCE) exhibits high electrocatalytic activity toward hydrazine (N2H4) at low potential and a linear response from 0.06 to 700 mu M with the detection limit for N2H4 was found to be 1.2 x 10(-8) M (S/N = 3). Based on scan rate effect during the hydrazine oxidation, it indicates that the number of electrons transferred in the rate-limiting step is 1, and a transfer coefficient (a) is estimated as 0.73. The self-assembled F-TiO2NTs-Au@Pd hybrid nanostructures as enhanced materials present excellent electrocatalytic activity, fast response, highly sensitive and have a promising application potential in nonenzymatic sensing. (C) 2013 Elsevier B.V. All rights reserved.
引用
收藏
页码:304 / 310
页数:7
相关论文
共 41 条
[1]   Electron transport and electrocatalytic properties of MWCNT/nickel nanocomposites: Hydrazine and diethylaminoethanethiol as analytical probes [J].
Adekunle, Abolanle S. ;
Ozoemena, Kenneth I. .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2010, 645 (01) :41-49
[2]   Rationally designed nanostructures for surface-enhanced Raman spectroscopy [J].
Banholzer, Matthew J. ;
Millstone, Jill E. ;
Qin, Lidong ;
Mirkin, Chad A. .
CHEMICAL SOCIETY REVIEWS, 2008, 37 (05) :885-897
[3]   Deposition of Pt, Pd, Ru and Au on the surfaces of titanate nanotubes [J].
Bavykin, Dmitry V. ;
Lapkin, Alexei A. ;
Plucinski, Pawel K. ;
Torrente-Murciano, Laura ;
Friedrich, Jens M. ;
Walsh, Frank C. .
TOPICS IN CATALYSIS, 2006, 39 (3-4) :151-160
[4]   Hydrothermal preparation of ZnO:CNT and TiO2:CNT composites and their photocatalytic applications [J].
Byrappa, K. ;
Dayananda, A. S. ;
Sajan, C. P. ;
Basavalingu, B. ;
Shayan, M. B. ;
Soga, K. ;
Yoshimura, M. .
JOURNAL OF MATERIALS SCIENCE, 2008, 43 (07) :2348-2355
[5]   Gold particle size effects in the gas-phase hydrogenation of m-dinitrobenzene over Au/TiO2 [J].
Cardenas-Lizana, Fernando ;
Gomez-Quero, Santiago ;
Idriss, Hicham ;
Keane, Mark A. .
JOURNAL OF CATALYSIS, 2009, 268 (02) :223-234
[6]   Surface-Enhanced Raman Scattering-Active Au/SiO2 Nanocomposites Prepared Using Sonoelectrochemical Pulse Deposition Methods [J].
Chang, Chun-Chao ;
Yang, Kuang-Hsuan ;
Liu, Yu-Chuan ;
Hsu, Ting-Chu ;
Mai, Fu-Der .
ACS APPLIED MATERIALS & INTERFACES, 2012, 4 (09) :4700-4707
[7]   Geometrically Controlled Nanoporous PdAu Bimetallic Catalysts with Tunable Pd/Au Ratio for Direct Ethanol Fuel Cells [J].
Chen, L. Y. ;
Chen, N. ;
Hou, Y. ;
Wang, Z. C. ;
Lv, S. H. ;
Fujita, T. ;
Jiang, J. H. ;
Hirata, A. ;
Chen, M. W. .
ACS CATALYSIS, 2013, 3 (06) :1220-1230
[8]   Nonenzymatic glucose sensor based on flower-shaped Au@Pd core-shell nanoparticles-ionic liquids composite film modified glassy carbon electrodes [J].
Chen, Xianlan ;
Pan, Hiabo ;
Liu, Hongfang ;
Du, Min .
ELECTROCHIMICA ACTA, 2010, 56 (02) :636-643
[9]   Chemisorption of 3-aminopropyltrimethoxysilane on Si(001)-(2 x 2) [J].
Demirel, G. ;
Cakmak, M. ;
Caykara, T. ;
Ellialtioglu, S. .
JOURNAL OF PHYSICAL CHEMISTRY C, 2007, 111 (41) :15020-15025
[10]   Understanding the Nucleation and Growth of Metals on TiO2: Co Compared to Au, Ni, and Pt [J].
Galhenage, Randima P. ;
Yan, Hui ;
Tenney, Samuel A. ;
Park, Nayoung ;
Henkelman, Graeme ;
Albrecht, Peter ;
Mullins, David R. ;
Chen, Donna A. .
JOURNAL OF PHYSICAL CHEMISTRY C, 2013, 117 (14) :7191-7201