Direct borohydride fuel cells

被引:237
作者
de Leon, CP
Walsh, FC [1 ]
Pletcher, D
Browning, DJ
Lakeman, JB
机构
[1] Univ Southampton, Sch Engn Sci, Electrochem Engn Grp, Southampton SO17 1BJ, Hants, England
[2] Univ Southampton, Sch Chem, Southampton SO17 1BJ, Hants, England
[3] Dept Phys Sci, Salisbury SP4 0QR, Wilts, England
关键词
borohydride; electrocatalysts; fuel cell; hydrogen membranes;
D O I
10.1016/j.jpowsour.2006.01.011
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The recent, rapid progress in the development of direct borohydride fuel cells is reviewed. Electrochemical reactions are considered together with the importance of operating parameters on cell performance. The advances in technology necessary for a widespread testing and more application of borohydride fuel cells are highlighted. A comparison of borohydride and methanol fuel cells shows that both system exhibit similar cell voltages, current and power densities despite that methanol cells operate at higher temperatures. The results are encouraging although more research is necessary, particularly in the synthesis of new electrocatalysts for borohydride oxidation. (c) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码:172 / 181
页数:10
相关论文
共 58 条
[1]  
Abe K., 1968, DENKI KAGAKU OYOBI K, V36, P788
[2]   A novel high power density borohydride-air cell [J].
Amendola, SC ;
Onnerud, P ;
Kelly, MT ;
Petillo, PJ ;
Sharp-Goldman, SL ;
Binder, M .
JOURNAL OF POWER SOURCES, 1999, 84 (01) :130-133
[3]   A safe, portable, hydrogen gas generator using aqueous borohydride solution and Ru catalyst [J].
Amendola, SC ;
Sharp-Goldman, SL ;
Janjua, MS ;
Spencer, NC ;
Kelly, MT ;
Petillo, PJ ;
Binder, M .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2000, 25 (10) :969-975
[4]   An ultrasafe hydrogen generator: aqueous, alkaline borohydride solutions and Ru catalyst [J].
Amendola, SC ;
Sharp-Goldman, SL ;
Janjua, MS ;
Kelly, MT ;
Petillo, PJ ;
Binder, M .
JOURNAL OF POWER SOURCES, 2000, 85 (02) :186-189
[5]  
[Anonymous], 1997, 1 COURSE ION PERMEAB
[6]  
BELLAVANCE MI, 1974, ENCY ELECTROCHEMISTR, V2
[7]   Development and operation of a 150 W air-feed direct methanol fuel cell stack [J].
Buttin, D ;
Dupont, M ;
Straumann, M ;
Gille, R ;
Dubois, JC ;
Ornelas, R ;
Fleba, GP ;
Ramunni, E ;
Antonucci, V ;
Aricò, AS ;
Cretì, P ;
Modica, E ;
Pham-Thi, M ;
Ganne, JP .
JOURNAL OF APPLIED ELECTROCHEMISTRY, 2001, 31 (03) :275-279
[8]   An alkaline direct borohydride fuel cell with hydrogen peroxide as oxidant [J].
Choudhury, NA ;
Raman, RK ;
Sampath, S ;
Shukla, AK .
JOURNAL OF POWER SOURCES, 2005, 143 (1-2) :1-8
[9]   Metal ammine complexes for hydrogen storage [J].
Christensen, CH ;
Sorensen, RZ ;
Johannessen, T ;
Quaade, UJ ;
Honkala, K ;
Elmoe, TD ;
Kohler, R ;
Norskov, JK .
JOURNAL OF MATERIALS CHEMISTRY, 2005, 15 (38) :4106-4108
[10]  
Dong H, 2003, INT J HYDROGEN ENERG, V28, P1095, DOI 10.1016/S0360-3199(02)00235-5