Fabrication of magnetically recoverable Fe3O4/CdS/g-C3N4 photocatalysts for effective degradation of ciprofloxacin under visible light

被引:46
作者
Zhang, Nan [1 ]
Li, Xuefei [1 ]
Wang, Yue [1 ]
Zhu, Bolin [1 ]
Yang, Jinghai [1 ]
机构
[1] Jilin Normal Univ, Key Lab Funct Mat Phys & Chem, Minist Educ, Changchun 130000, Peoples R China
关键词
Photocatalytic activity; Fe3O4/CdS/g-C3N4; heterostructure; Magnetic separation; Ciprofloxacin; Visible light; CDS NANOPARTICLES; ANTIBIOTIC CIPROFLOXACIN; COMPOSITE PHOTOCATALYSTS; HYDROGEN-PRODUCTION; LITHIUM STORAGE; SHELL THICKNESS; CARBON NITRIDE; H-2; PRODUCTION; NANOCOMPOSITES; HETEROJUNCTION;
D O I
10.1016/j.ceramint.2020.05.158
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Photocatalytic technology is an environmentally safe method of eliminating organic pollutants and antibiotics in wastewater. In this research, the performance of Fe3O4/CdS/g-C3N4 (FCN) photocatalyst for degradation of antibiotics was studied. The composite photocatalysts with different concentrations of g-C3N4 were prepared. FCN has better photocatalytic activity than degradation dyes in removal of antibiotics under visible light. This indicates that FCN could effectively hinder the recombination of carriers, and the addition of g-C3N4 increases the optical response range of CdS. At the same time, the introduction of Fe3O4 magnetic nanoparticles overcomes the problem of difficulty in recovery of the powder photocatalyst. The photocatalytic activity is not reduced to any significant after three cycles of use.
引用
收藏
页码:20974 / 20984
页数:11
相关论文
共 68 条
[1]   Graphitic carbon nitride-based photocatalysts: Toward efficient organic transformation for value-added chemicals production [J].
Akhundi, Anise ;
Badiei, Alireza ;
Ziarani, Ghodsi Mohammadi ;
Habibi-Yangjeh, Aziz ;
Munoz-Batista, Mario J. ;
Luque, Rafael .
MOLECULAR CATALYSIS, 2020, 488
[2]   Review on photocatalytic conversion of carbon dioxide to value-added compounds and renewable fuels by graphitic carbon nitride-based photocatalysts [J].
Akhundi, Anise ;
Habibi-Yangjeh, Aziz ;
Abitorabi, Masoud ;
Pouran, Shima Rahim .
CATALYSIS REVIEWS-SCIENCE AND ENGINEERING, 2019, 61 (04) :595-628
[3]   Fabrication of g-C3N4/TiO2 heterojunction composite for enhanced photocatalytic hydrogen production [J].
Alcudia-Ramos, M. A. ;
Fuentez-Torres, M. O. ;
Ortiz-Chi, F. ;
Espinosa-Gonzalez, C. G. ;
Hernandez-Como, N. ;
Garcia-Zaleta, D. S. ;
Kesarla, M. K. ;
Torres-Torres, J. G. ;
Collins-Martinez, V. ;
Godavarthi, S. .
CERAMICS INTERNATIONAL, 2020, 46 (01) :38-45
[4]   Kinetics and mechanism of advanced oxidation processes (AOPs) in degradation of ciprofloxacin in water [J].
An, Taicheng ;
Yang, Hai ;
Li, Guiying ;
Song, Weihua ;
Cooper, William J. ;
Nie, Xiangping .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2010, 94 (3-4) :288-294
[5]   Electrochemical incineration of the antibiotic ciprofloxacin in sulfate medium and synthetic urine matrix [J].
Antonin, Vanessa S. ;
Santos, Mauro C. ;
Garcia-Segura, Sergi ;
Brillas, Enric .
WATER RESEARCH, 2015, 83 :31-41
[6]   Fabrication of novel g-C3N4 nanosheet/carbon dots/Ag6Si2O7 nanocomposites with high stability and enhanced visible-light photocatalytic activity [J].
Asadzadeh-Khaneghah, Soheila ;
Habibi-Yangjeh, Aziz ;
Vadivel, S. .
JOURNAL OF THE TAIWAN INSTITUTE OF CHEMICAL ENGINEERS, 2019, 103 :94-109
[7]   Decoration of carbon dots over hydrogen peroxide treated graphitic carbon nitride: Exceptional photocatalytic performance in removal of different contaminants under visible light [J].
Asadzadeh-Khaneghah, Soheila ;
Habibi-Yangjeh, Aziz ;
Nakata, Kazuya .
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2019, 374 :161-172
[8]   A novel application of g-C3N4 thin film in photoelectrochemical anticorrosion [J].
Bu, Yuyu ;
Chen, Zhuoyuan ;
Yu, Jianqiang ;
Li, Weibing .
ELECTROCHIMICA ACTA, 2013, 88 :294-300
[9]   Study on the separation mechanisms of photogenerated electrons and holes for composite photocatalysts g-C3N4-WO3 [J].
Chen, Shifu ;
Hu, Yingfei ;
Meng, Sugang ;
Fu, Xianliang .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2014, 150 :564-573
[10]   Au-CdS Core-Shell Nanocrystals with Controllable Shell Thickness and Photoinduced Charge Separation Property [J].
Chen, Wei-Ta ;
Yang, Ting-Ting ;
Hsu, Yung-Jung .
CHEMISTRY OF MATERIALS, 2008, 20 (23) :7204-7206