Visible light-induced selective hydrobromodifluoromethylation of alkenes with dibromodifluoromethane

被引：75
作者：
Lin, Qing-Yu [1 ]
Xu, Xiu-Hua [1 ]
Qing, Feng-Ling [1 ,2 ]
机构：
[1] Chinese Acad Sci, Shanghai Inst Organ Chem, Key Lab Organofluorine Chem, Shanghai 200032, Peoples R China
[2] Donghua Univ, Coll Chem Chem Engn & Biotechnol, Shanghai 201620, Peoples R China
来源：
ORGANIC & BIOMOLECULAR CHEMISTRY | 2015年 / 13卷 / 32期
基金：
中国国家自然科学基金;
关键词：
TRANSFER RADICAL-ADDITION; ETHYL 3-BROMO-3,3-DIFLUOROPROPIONATE; CATALYTIC HYDROTRIFLUOROMETHYLATION; TRIFLUOROMETHYLATION REACTIONS; ALPHA-TRIFLUOROMETHYLATION; STEREOSELECTIVE-SYNTHESIS; PHOTOREDOX; FLUORINE; EFFICIENT; BROMODIFLUOROMETHYLATION;
D O I：
10.1039/c5ob01302j
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A visible light-induced selective hydrobromodifluoromethylation of alkenes using CF2Br2 was developed. This transformation proceeded smoothly in the presence of catalytic eosin Y at room temperature to give various hydrobromodifluoromethylated compounds with broad functional group tolerance.
引用
收藏
页码：8740 / 8749
页数：10
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