Solid-Phase Organic Synthesis of Aryl Vinyl Ethers Using Sulfone-Linking Strategy

被引：8

作者：

Yu Lamei ^{[1
]}

Tang Ni ^{[1
]}

Sheng Shouri ^{[1
]}

Chen Rubing ^{[1
]}

Liu Xiaoling ^{[1
]}

Cai Mingzhong ^{[1
]}

机构：

[1] Jiangxi Normal Univ, Coll Chem & Chem Engn, Nanchang 330022, Jiangxi, Peoples R China

来源：

CHINESE JOURNAL OF CHEMISTRY | 2012年 / 30卷 / 05期

基金：

中国国家自然科学基金;

关键词：

solid-phase organic synthesis; aryl vinyl ether; polystyrene-supported; 2-phenylsulfonylethanol; sulfone-linking; Suzuki coupling reaction; DIELS-ALDER REACTIONS; SODIUM BENZENESULFINATE; EFFICIENT; SELENIDE; LINKERS;

D O I：

10.1002/cjoc.201100451

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel facile solid-phase organic synthesis of aryl vinyl ethers by reaction of polystyrene-supported 2-phenylsulfonylethanol with phenols under Mitsunobu conditions and subsequent elimination reaction with DBU has been developed. The advantages of this method include straightforward operation, good yield and high purity of the products. Alternatively, a typical example of Suzuki coupling reaction on-resin was further applied to prepare 4-phenylphenyl vinyl ether for extending this method.

引用

页码：1027 / 1030

页数：4

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