Triazole-Based One-Dimensional Spin-Crossover Coordination Polymers

被引：243

作者：

Roubeau, Olivier ^{[1
,2
]}

机构：

[1] CSIC, Inst Ciencia Mat Aragon ICMA, E-50009 Zaragoza, Spain

[2] Univ Zaragoza, E-50009 Zaragoza, Spain

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2012年 / 18卷 / 48期

关键词：

coordination polymers; iron; magnetic properties; spin crossover; triazoles; TRANSITION MOLECULAR MATERIALS; LANGMUIR-BLODGETT-FILMS; THERMAL HYSTERESIS LOOP; ISING-LIKE SYSTEMS; MAGNETIC-PROPERTIES; IRON(II) COMPOUNDS; CRYSTAL-STRUCTURE; PHASE-TRANSITION; 1,2,4-TRIAZOLE COMPLEXES; MOSSBAUER-SPECTROSCOPY;

D O I：

10.1002/chem.201201647

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

One-dimensional coordination FeII polymers constructed through triple N1,N2-1,2,4-triazole bridges form a unique class of spin-crossover materials, the synthetic versatility of which allows tuning the spin-crossover properties, the design of gels, films, liquid crystals, and nanoparticles and single-particle addressing. This Minireview provides the first complete overview of these very attractive switchable materials and their most recent developments.

引用

页码：15230 / 15244

页数：15

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