The PZT system (PbTixZr1-xO3, 0 ≤ x ≤ 1.0): The real phase diagram of solid solutions (room temperature) (Part 2)

被引：14
|
作者：
Andryushina, I. N. [1 ]
Reznichenko, L. A. [1 ]
Shilkina, L. A. [1 ]
Andryushin, K. P. [1 ]
Dudkina, S. I. [1 ]
机构：
[1] So Fed Univ, Inst Phys Res, Rostov Na Donu 344090, Russia
来源：
CERAMICS INTERNATIONAL | 2013年 / 39卷 / 02期
关键词：
PZT; Phase diagram; Room temperature; Point defects; TRICRITICAL BEHAVIOR; TRANSITIONS; TITANATE; OXIDES;
D O I：
10.1016/j.ceramint.2012.07.060
中图分类号：
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号：
0805 ; 080502 ;
摘要：
The sequence of phase transformations in the ceramic system PbTixZr1-xO3 (0 <= x <= 1.0) is determined and the real phase diagram of solid solutions is built. The observed periodicity of phase formation processes in the rhombohedral and tetragonal regions is explained by the real (defective) structure of PZT system ceramics, which is in many respects related to the variable valence of Ti ions and, as a result, to formation, accumulation, and ordering of point defects (oxygen vacancies) and their elimination by crystallographic shifts. The obtained results are useful in interpretation of the macroscopic properties of ceramics based on the PZT system. Crown Copyright (C) 2012 Published by Elsevier Ltd and Techna Group S.r.l. All rights reserved.
引用
收藏
页码：1285 / 1292
页数：8
相关论文
共 50 条
  • [31] Phase diagram of Rb2xTl2(1-x)Cd2(SO4)3 solid solutions
    Vlokh, R
    Girnyk, I
    Martunyuk-Lototska, I
    Czapla, Z
    Dacko, S
    Kosturek, B
    FERROELECTRICS, 2004, 303 : 51 - 54
  • [32] PHASE-DIAGRAM OF MAGNETIC STATE OF MN2-XZNXSB(0-LESS-THAN-OR-EQUAL-TO-X-LESS-THAN-OR-EQUAL-TO-1.0) SOLID-SOLUTION SYSTEM
    DYMONT, VP
    MAKOVETSKII, GI
    RYZHKOVSKII, VM
    FIZIKA TVERDOGO TELA, 1994, 36 (10): : 2916 - 2925
  • [33] Formation and characterization of the solid solutions (CrxFe1-x)(2)O-3, 0<=x<=1
    Music, S
    Lenglet, M
    Popovic, S
    Hannoyer, B
    CzakoNagy, I
    Ristic, M
    Balzar, D
    Gashi, F
    JOURNAL OF MATERIALS SCIENCE, 1996, 31 (15) : 4067 - 4076
  • [34] Thermal expansion, T - x phase diagram and polarization of (1-x)Na1/2Bi1/2TiO3-xBaTiO3 solid solutions
    Gorev, M. V.
    Flerov, I. N.
    Molokeev, M. S.
    Bormanis, K.
    Birks, E.
    Sapozhnikov, S. V.
    Mikhaleva, E. A.
    JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 2024, 44 (15)
  • [35] Magnetic phase diagram of Co x Zn1-x Cr2S4 solid solutions
    Aminov, T. G.
    Shabunina, G. G.
    Busheva, E. V.
    Novotortsev, V. M.
    INORGANIC MATERIALS, 2017, 53 (11) : 1136 - 1149
  • [36] Performance of cobalt catalysts supported on CexZr1−xO2 (0 < x < 1) solid solutions in oxidative ethanol reforming
    Thaisa A. Maia
    José M. Assaf
    Elisabete M. Assaf
    Reaction Kinetics, Mechanisms and Catalysis, 2013, 109 : 181 - 197
  • [37] Coprecipitation synthesis and optical absorption property of Zn2TixSn1–xO4 (0 ≤ x ≤ 1) solid solutions
    Cun Wang
    Bo-Qing Xu
    Journal of Materials Science, 2009, 44 : 919 - 925
  • [38] Electrical and Magnetic Properties of Spinel Solid Solutions Mg2-xTi1+xO4; 0 o x o 1
    J Solid State Chem, 2 (216):
  • [39] First principles phase diagram calculations for the octahedral-interstitial system HfOX, 0 ≤ X ≤ 1/2
    Burton, Benjamin Paul
    van de Walle, Axel
    CALPHAD-COMPUTER COUPLING OF PHASE DIAGRAMS AND THERMOCHEMISTRY, 2012, 37 : 151 - 157
  • [40] First Principles Phase Diagram Calculations for the Octahedral-Interstitial System ZrOX, 0 ≤ X ≤ 1/2
    Burton, Benjamin Paul
    van de Walle, Axel
    Stokes, Harold T.
    JOURNAL OF THE PHYSICAL SOCIETY OF JAPAN, 2012, 81 (01)
12345