The PZT system (PbTixZr1-xO3, 0 ≤ x ≤ 1.0): The real phase diagram of solid solutions (room temperature) (Part 2)

被引：14
|
作者：
Andryushina, I. N. [1 ]
Reznichenko, L. A. [1 ]
Shilkina, L. A. [1 ]
Andryushin, K. P. [1 ]
Dudkina, S. I. [1 ]
机构：
[1] So Fed Univ, Inst Phys Res, Rostov Na Donu 344090, Russia
来源：
CERAMICS INTERNATIONAL | 2013年 / 39卷 / 02期
关键词：
PZT; Phase diagram; Room temperature; Point defects; TRICRITICAL BEHAVIOR; TRANSITIONS; TITANATE; OXIDES;
D O I：
10.1016/j.ceramint.2012.07.060
中图分类号：
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号：
0805 ; 080502 ;
摘要：
The sequence of phase transformations in the ceramic system PbTixZr1-xO3 (0 <= x <= 1.0) is determined and the real phase diagram of solid solutions is built. The observed periodicity of phase formation processes in the rhombohedral and tetragonal regions is explained by the real (defective) structure of PZT system ceramics, which is in many respects related to the variable valence of Ti ions and, as a result, to formation, accumulation, and ordering of point defects (oxygen vacancies) and their elimination by crystallographic shifts. The obtained results are useful in interpretation of the macroscopic properties of ceramics based on the PZT system. Crown Copyright (C) 2012 Published by Elsevier Ltd and Techna Group S.r.l. All rights reserved.
引用
收藏
页码：1285 / 1292
页数：8
相关论文
共 50 条
  • [1] The PZT system (PbTixZr1-xO3, 0 ≤ x ≤ 1.0): High temperature X-ray diffraction studies. Complete x-T phase diagram of real solid solutions (Part 3)
    Andryushina, I. N.
    Reznichenko, L. A.
    Shilkina, L. A.
    Andryushin, K. P.
    Dudkina, S. I.
    CERAMICS INTERNATIONAL, 2013, 39 (03) : 2889 - 2901
  • [2] The PZT system (PbTixZr1-xO3, 0≤x≤1.0): The dependences of electrophysical properties of solid solutions on the electric field strength and component concentration (Part 5)
    Andryushina, I. N.
    Reznichenko, L. A.
    Shilkina, L. A.
    Andryushin, K. P.
    Yurasov, Yu I.
    Dudkina, S. I.
    CERAMICS INTERNATIONAL, 2013, 39 (07) : 7635 - 7640
  • [3] The PZT system (PbTixZr1-xO3, 0 ≤ x ≤ 1.0): Dielectric response of solid solutions in broad temperature (10 ≤ T ≤ 1000 K) and frequency (10-2 ≤ f ≤ 107 Hz) ranges (Part 4)
    Andryushina, I. N.
    Reznichenko, L. A.
    Shmytko, I. M.
    Shilkina, L. A.
    Andryushin, K. P.
    Yurasov, Yu. I.
    Dudkina, S. I.
    CERAMICS INTERNATIONAL, 2013, 39 (04) : 3979 - 3986
  • [4] ON THE ORIGIN OF 2-PHASE MORPHOTROPIC REGION OF THE SYSTEM PBTIXZR1-XO3
    DERGUNOVA, NV
    SAKHNENKO, VR
    IZVESTIYA AKADEMII NAUK SERIYA FIZICHESKAYA, 1993, 57 (06): : 42 - 44
  • [5] The PZT system (PbZr1-xTixO3, 0.0 ≤ x ≤ 1.0): Specific features of recrystallization sintering and microstructures of solid solutions (Part 1)
    Andryushina, I. N.
    Reznichenko, L. A.
    Alyoshin, V. A.
    Shilkina, L. A.
    Titov, S. V.
    Titov, V. V.
    Andryushin, K. P.
    Dudkina, S. I.
    CERAMICS INTERNATIONAL, 2013, 39 (01) : 753 - 761
  • [6] Phase diagram of the system of (1-N...)BiFeO3-x PbFe0.5Nb0.5O3 solid solutions at room temperature
    Shilkina, L. A.
    Pavlenko, A. V.
    Reznitchenko, L. A.
    Verbenko, I. A.
    CRYSTALLOGRAPHY REPORTS, 2016, 61 (02) : 263 - 269
  • [7] Phase diagram of the system of (1–х)BiFeO3–xPbFe0.5Nb0.5O3 solid solutions at room temperature
    L. A. Shilkina
    A. V. Pavlenko
    L. A. Reznitchenko
    I. A. Verbenko
    Crystallography Reports, 2016, 61 : 263 - 269
  • [8] Synthesis of solid solutions of DyxBi2-xO3 with x=0, 1 and 2: Structural, optical and ac impedance analysis
    Iyyapushpam, S.
    Iekha, P. Chithra
    Padiyan, D. Pathinettam
    PHYSICA B-CONDENSED MATTER, 2010, 405 (02) : 712 - 719
  • [9] Phase x-T diagram of actual solid solutions of the (1 − x)PbZrO3-xPbTiO3 system (0.37 ≤ x ≤ 0.57)
    L. A. Reznichenko
    L. A. Shilkina
    O. N. Razumovskaya
    E. A. Yaroslavtseva
    S. I. Dudkina
    O. A. Demchenko
    Yu. I. Yurasov
    A. A. Esis
    I. N. Andryushina
    Physics of the Solid State, 2008, 50 : 1527 - 1533
  • [10] Phase transition in Eu2Zr2-xO7-2x (x=0-1) solid solutions: A combined structural and spectroscopic study
    Kong, Linggen
    Wang, Zhiyang
    Karatchevtseva, Inna
    Zhang, Yingjie
    JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2024, 107 (11) : 7604 - 7618
12345