Coordination-directed self-assembly of a simple benzothiadiazole-fused tetrathiafulvalene to low-bandgap metallogels

被引:33
作者
Amacher, Anneliese M. [1 ]
Puigmarti-Luis, Josep [2 ,3 ]
Geng, Yan [1 ]
Lebedev, Victor [2 ]
Laukhin, Vladimir [2 ,4 ]
Kraemer, Karl [1 ]
Hauser, Juerg [1 ]
Amabilino, David B. [2 ,5 ]
Decurtins, Silvio [1 ]
Liu, Shi-Xia [1 ]
机构
[1] Univ Bern, Dept Chem & Biochem, CH-3012 Bern, Switzerland
[2] Inst Ciencia Mat Barcelona ICMAB CSIC, Catalonia 08193, Spain
[3] Empa, Lab Protect & Physiol, CH-9014 St Gallen, Switzerland
[4] ICREA, Barcelona, Spain
[5] Univ Nottingham, Sch Chem, Nottingham NG7 2RD, England
基金
英国工程与自然科学研究理事会; 瑞士国家科学基金会;
关键词
CHARGE-TRANSFER; ELECTRICAL-CONDUCTIVITY; STACKING INTERACTIONS; TRANSPORT-PROPERTIES; MAGNETIC-PROPERTIES; GEL; POLYMERS; CRYSTAL; GELATOR; SYSTEMS;
D O I
10.1039/c5cc06819c
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Coordination-driven gelation of a benzothiadiazole-fused tetrathiafulvalene (TTF) is demonstrated. This is the first work reporting highly stable metallogels based on a donor-acceptor conjugate with such a simple structure for the construction of new low-bandgap materials with various functional properties and novel nanostructures.
引用
收藏
页码:15063 / 15066
页数:4
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