UV cured polymer based on a renewable cardanol derived RAFT agent

被引:23
作者
Cheng, Chuanjie [1 ]
Bai, Xiongxiong [1 ]
Liu, Shaojin [1 ]
Huang, Qinghua [1 ]
Tu, Yuanming [1 ]
Wu, Haiming [1 ]
Wang, Xiaoji [1 ]
机构
[1] Jiangxi Sci & Technol Normal Univ, Jiangxi Key Lab Organ Chem, Nanchang 330013, Jiangxi, Peoples R China
关键词
Cardanol; Reversible addition-fragmentation chain transfer (RAFT) agent; Reactive surfactant; UV curing; Emulsion polymerization; TRANSFER RADICAL POLYMERIZATION; ONE-POT SYNTHESIS; BLOCK-COPOLYMERS; EMULSION; SURFACTANT; ATRP; METHACRYLATE; MONOMERS;
D O I
10.1007/s10965-013-0197-2
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
A cardanol-derived reversible addition-fragmentation chain transfer (RAFT) agent was synthesized in 57 % total yield, and a cardanol-based anionic surfactant was also facilely prepared. Emulsion polymerization of methyl methacrylate (MMA) was realized to form a cardanol-terminated PMMA polymer by using the novel RAFT agent as well as the cardanol-based anionic surfactant. To improve the properties of cardanol-terminated PMMA as a material, UV-curing was performed. According to the comprehensive behavior of the UV-cured resins, optimal irradiation time was 20 min.
引用
收藏
页数:11
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