One-pot synthesis of benzamide over a robust tandem catalyst based on center radially fibrous silica encapsulated TS-1

被引：64

作者：

Peng, Hong-gen ^{[1
]}

Xu, Le ^{[1
]}

Wu, Haihong ^{[1
]}

Zhang, Kun ^{[1
]}

Wu, Peng ^{[1
]}

机构：

[1] E China Normal Univ, Dept Chem, Shanghai Key Lab Green Chem & Chem Proc, Shanghai 200062, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2013年 / 49卷 / 26期

关键词：

PRIMARY AMIDES; SHELL; CORE; ALDOXIMES;

D O I：

10.1039/c3cc38546a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A center radially fibrous silica encapsulated TS-1 zeolite (TS-1@KCC-1) has been synthesized in a microemulsion system for the first time. Supporting the Rh(OH)(3) species, this novel core-shell structured material serves as a robust bifunctional catalyst for one-pot synthesis of benzamide from benzaldehyde, ammonia and hydrogen peroxide, in which the aldehyde ammoximation and oxime rearrangement occur in a tandem way.

引用

页码：2709 / 2711

页数：3

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