Titania modified SBA-15 as the support for molybdenum based catalysts

被引:0
作者
Laniecki, M [1 ]
Wojtowski, N [1 ]
机构
[1] Adam Mickiewicz Univ, Fac Chem, PL-60780 Poznan, Poland
来源
MOLECULAR SIEVES: FROM BASIC RESEARCH TO INDUSTRIAL APPLICATIONS, PTS A AND B | 2005年 / 158卷
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中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The series of titania modified SBA-15 supports were prepared in post synthesis applying titanium isopropoxide solutions and appropriate amounts of SBA-15. These Supports were used for preparation of molybdenum based catalysts. Ammonium heptamolybdate and molydenum carbonyl were applied as the source of Mo. Results confirm that this method of molydenum catalysts synthesis do not cause significant changes in symmetry of SBA-15. The decrease of surface area and channel dimensions are the main effects of SBA-15 modifications both with TiO2 and Mo species. Only Lewis acid sites were Found upon incorporation of titania on SBA-15. The use of different Sources of Mo leads towards different oxidized molybdenum Species which call be attractive in generation of their sulfided or nitrided forms.
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页码:757 / 764
页数:8
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