19F NMR in organometallic chemistry Applications of fluorinated aryls

被引：57
作者：
Espinet, Pablo [1 ]
Albeniz, Ana C. [1 ]
Casares, Juan A. [1 ]
Martinez-Ilarduya, Jesus M. [1 ]
机构：
[1] Univ Valladolid, Fac Ciencias, IU CINQUIMA Quim Inorgan, E-47011 Valladolid, Spain
来源：
COORDINATION CHEMISTRY REVIEWS | 2008年 / 252卷 / 21-22期
关键词：
Nuclear magnetic resonance; Fluoroaryl; Fluorinated group; Chemical exchange; Fluxionality; Kinetics; C-F cleavage;
D O I：
10.1016/j.ccr.2007.12.024
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The applications of F-19 NMR in the study of a number of problems in organometallic chemistry are illustrated with relevant cases, paying special attention to the case of molecules containing fluorinated aryls. These are used as reporter groups of molecular symmetry, fluxional processes, and chemical changes, and help in the study of many fundamental organometallic processes. (C) 2007 Elsevier B.V. All rights reserved.
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收藏
页码：2180 / 2208
页数：29
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