Metal-Organic Frameworks via Emissive Metal-Carboxylate Zwitterion Intermediates

被引：16

作者：

Armaghan, Mahsa ^{[1
,2
]}

Shang, Xiu-Juan ^{[4
]}

Yuan, Yan-Qiu ^{[4
]}

Young, David J. ^{[1
,3
]}

Zhang, Wen-Hua ^{[1
,4
]}

Hor, T. S. Andy ^{[1
,2
]}

Lang, Jian-Ping ^{[4
]}

机构：

[1] Agcy Sci Technol & Res, Inst Mat Res & Engn, Singapore 117602, Singapore

[2] Natl Univ Singapore, Dept Chem, Singapore 117543, Singapore

[3] Monash Univ, Sch Sci, Bandar Sunway 47500, Selangor De, Malaysia

[4] Soochow Univ, Coll Chem, Chem Engn & Mat Sci, Suzhou 215123, Peoples R China

来源：

CHEMPLUSCHEM | 2015年 / 80卷 / 08期

基金：

中国国家自然科学基金;

关键词：

metal-carboxylate zwitterions; metal-organic frameworks; photoluminescence; SINGLE-CRYSTAL; CO2; ADSORPTION; POROUS MATERIAL; SORPTION; CLUSTERS; EXCHANGE; LINKERS; OXIDATION; MN-4; MOF;

D O I：

10.1002/cplu.201500134

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Pyridinemethanol-carboxylate esters form octahedral complexes with Zn(NO3)(2) in aqueous DMF that subsequently undergo hydrolysis at elevated temperatures to form metal-carboxylate zwitterions. In situ deprotonation of the hydroxy group leads to thermally robust, neutral MOFs. This stepwise synthesis can be controlled by temperature and is made possible by the subtle difference in reactivity of the functional groups.

引用

页码：1231 / 1234

页数：4

共 77 条

[41]

PADIAL NM, 2013, ANGEW CHEM, V0125

[42] Enhanced isosteric heat, selectivity, and uptake capacity of CO2 adsorption in a metal-organic framework by impregnated metal ions [J].

Park, Hye Jeong ;

Suh, Myunghyun Paik .

CHEMICAL SCIENCE, 2013, 4 (02) :685-690

[43] Solid-state conversion of a MOF to a metal-organo polymeric framework ( MOPF) via [2+2] cycloaddition reaction [J].

Park, In-Hyeok ;

Chanthapally, Anjana ;

Lee, Hyeong-Hwan ;

Quah, Hong Sheng ;

Lee, Shim Sung ;

Vittal, Jagadese J. .

CHEMICAL COMMUNICATIONS, 2014, 50 (28) :3665-3667

[44]

Park J., 2015, Angew. Chem. Int. Ed, V54, P430, DOI DOI 10.1002/ANGE.201408862

[45] Photochromic Metal-Organic Frameworks: Reversible Control of Singlet Oxygen Generation [J].

Park, Jihye ;

Feng, Dawei ;

Yuan, Shuai ;

Zhou, Hong-Cai .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2015, 54 (02) :430-+

[46] The Mechanism of Carbon Dioxide Adsorption in an Alkylamine-Functionalized Metal-Organic Framework [J].

Planas, Nora ;

Dzubak, Allison L. ;

Poloni, Roberta ;

Lin, Li-Chiang ;

McManus, Alison ;

McDonald, Thomas M. ;

Neaton, Jeffrey B. ;

Long, Jeffrey R. ;

Smit, Berend ;

Gagliardi, Laura .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2013, 135 (20) :7402-7405

[47] Photochemical cycloaddition on the pore surface of a porous coordination polymer impacts the sorption behavior [J].

Sato, Hiroshi ;

Matsuda, Ryotaro ;

Mir, Mohammad Hedayetullah ;

Kitagawa, Susumu .

CHEMICAL COMMUNICATIONS, 2012, 48 (64) :7919-7921

[48] A Family of Porous Lonsdaleite-e Networks Obtained through Pillaring of Decorated Kagome Lattice Sheets [J].

Schoedel, Alexander ;

Boyette, Wesley ;

Wojtas, Lukasz ;

Eddaoudi, Mohamed ;

Zaworotko, Michael J. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2013, 135 (38) :14016-14019

[49] Solid-state structural transformation doubly triggered by reaction temperature and time in 3D metal-organic frameworks: great enhancement of stability and gas adsorption [J].

Shen, Ping ;

He, Wen-Wen ;

Du, Dong-Ying ;

Jiang, Hai-Long ;

Li, Shun-Li ;

Lang, Zhong-Ling ;

Su, Zhong-Min ;

Fu, Qiang ;

Lan, Ya-Qian .

CHEMICAL SCIENCE, 2014, 5 (04) :1368-1374

[50] Selective Turn-On Ammonia Sensing Enabled by High-Temperature Fluorescence in Metal-Organic Frameworks with Open Metal Sites [J].

Shustova, Natalia B. ;

Cozzolino, Anthony F. ;

Reineke, Sebastian ;

Baldo, Marc ;

Dinca, Mircea .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2013, 135 (36) :13326-13329

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