Metal-Organic Frameworks via Emissive Metal-Carboxylate Zwitterion Intermediates

被引：16

作者：

Armaghan, Mahsa ^{[1
,2
]}

Shang, Xiu-Juan ^{[4
]}

Yuan, Yan-Qiu ^{[4
]}

Young, David J. ^{[1
,3
]}

Zhang, Wen-Hua ^{[1
,4
]}

Hor, T. S. Andy ^{[1
,2
]}

Lang, Jian-Ping ^{[4
]}

机构：

[1] Agcy Sci Technol & Res, Inst Mat Res & Engn, Singapore 117602, Singapore

[2] Natl Univ Singapore, Dept Chem, Singapore 117543, Singapore

[3] Monash Univ, Sch Sci, Bandar Sunway 47500, Selangor De, Malaysia

[4] Soochow Univ, Coll Chem, Chem Engn & Mat Sci, Suzhou 215123, Peoples R China

来源：

CHEMPLUSCHEM | 2015年 / 80卷 / 08期

基金：

中国国家自然科学基金;

关键词：

metal-carboxylate zwitterions; metal-organic frameworks; photoluminescence; SINGLE-CRYSTAL; CO2; ADSORPTION; POROUS MATERIAL; SORPTION; CLUSTERS; EXCHANGE; LINKERS; OXIDATION; MN-4; MOF;

D O I：

10.1002/cplu.201500134

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Pyridinemethanol-carboxylate esters form octahedral complexes with Zn(NO3)(2) in aqueous DMF that subsequently undergo hydrolysis at elevated temperatures to form metal-carboxylate zwitterions. In situ deprotonation of the hydroxy group leads to thermally robust, neutral MOFs. This stepwise synthesis can be controlled by temperature and is made possible by the subtle difference in reactivity of the functional groups.

引用

页码：1231 / 1234

页数：4

共 77 条

[1]

[Anonymous], 2009, ANGEW CHEM

[2]

[Anonymous], 2021, ANGEW CHEM, DOI DOI 10.1002/ANGE.201302682

[3] Ti3+-, V2+/3+-, Cr2+/3+-, Mn2+-, and Fe2+-Substituted MOF-5 and Redox Reactivity in Cr- and Fe-MOF-5 [J].

Brozek, Carl K. ;

Dinca, Mircea .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2013, 135 (34) :12886-12891

[4] Heterometallic Modular Metal-Organic 3D Frameworks Assembled via New Tris-β-Diketonate Metalloligands: Nanoporous Materials for Anion Exchange and Scaffolding of Selected Anionic Guests [J].

Carlucci, Lucia ;

Ciani, Gianfranco ;

Maggini, Simona ;

Proserpio, Davide M. ;

Visconti, Marco .

CHEMISTRY-A EUROPEAN JOURNAL, 2010, 16 (41) :12328-12341

[5] Postsynthetic Methods for the Functionalization of Metal-Organic Frameworks [J].

Cohen, Seth M. .

CHEMICAL REVIEWS, 2012, 112 (02) :970-1000

[6] Metal-Organic Frameworks and Self-Assembled Supramolecular Coordination Complexes: Comparing and Contrasting the Design, Synthesis, and Functionality of Metal-Organic Materials [J].

Cook, Timothy R. ;

Zheng, Yao-Rong ;

Stang, Peter J. .

CHEMICAL REVIEWS, 2013, 113 (01) :734-777

[7]

Deshpande R.K., 2010, Angew. Chem, V122, P4702, DOI 10.1002/ange.200905960

[8] Thermo labile Groups in Metal-Organic Frameworks: Suppression of Network Interpenetration, Post-Synthetic Cavity Expansion, and Protection of Reactive Functional Groups [J].

Deshpande, Rajesh K. ;

Minnaar, Jozeph L. ;

Telfer, Shane G. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (27) :4598-4602

[9] Microporous manganese formate: A simple metal-organic porous material with high framework stability and highly selective gas sorption properties [J].

Dybtsev, DN ;

Chun, H ;

Yoon, SH ;

Kim, D ;

Kim, K .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (01) :32-33

[10] Novel metal-organic framework linkers for light harvesting applications [J].

Foster, Michael E. ;

Azoulay, Jason D. ;

Wong, Bryan M. ;

Allendorf, Mark D. .

CHEMICAL SCIENCE, 2014, 5 (05) :2081-2090

← 1 2 3 4 5 6 7 8 →