Chemistry of Soft Porous Crystals: Structural Dynamics and Gas Adsorption Properties

被引：275

作者：

Krause, Simon ^{[1
]}

Hosono, Nobuhiko ^{[2
]}

Kitagawa, Susumu ^{[3
]}

机构：

[1] Univ Groningen, Stratingh Inst Chem, Nijenborgh 4, NL-9747 AG Groningen, Netherlands

[2] Univ Tokyo, Grad Sch Frontier Sci, Dept Adv Mat Sci, Kashiwa, Chiba 2778561, Japan

[3] Kyoto Univ, Inst Adv Study, Inst Integrated Cell Mat Sci, Sakyo Ku, Kyoto 6068501, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2020年 / 59卷 / 36期

基金：

日本科学技术振兴机构;

关键词：

flexible metal-organic frameworks; gas adsorption; hysteretic sorption; porous crystals; METAL-ORGANIC-FRAMEWORKS; TRANSMISSION ELECTRON-MICROSCOPY; LAYER COORDINATION POLYMER; MECHANICAL-PROPERTIES; MOLECULAR-DYNAMICS; HYSTERETIC SORPTION; INDUCED DEFORMATION; GUEST MOLECULES; SOLID-SOLUTIONS; CO2; CAPTURE;

D O I：

10.1002/anie.202004535

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In this Minireview, we discuss the fundamental chemistry of soft porous crystals (SPCs) by characterizing their common structural features and the resulting structural softness and transitions. In particular, we focus on the recently emerging properties based on metastable transitions and those arising from local dynamics. By comparing the resulting adsorption properties to those of commonly applied rigid adsorbents, we highlight the potential of SPCs to revolutionize adsorption-based technologies, considering our current understanding of the thermodynamic and kinetic aspects. We provide brief outlines for the experimental and computational characterization of such phenomena and offer an outlook toward next-generation SPCs likely to be discovered in the next decade.

引用

页码：15325 / 15341

页数：17

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