Photoinduced strategies towards strained molecules

被引:69
作者
Pramanik, Mukund M. D. [1 ]
Qian, Hao [1 ]
Xiao, Wen-Jing [1 ]
Chen, Jia-Rong [1 ]
机构
[1] Cent China Normal Univ, Minist Educ, CCNU uOttawa Joint Res Ctr, Coll Chem,Key Lab Pesticides & Chem Biol, 152 Luoyu Rd, Wuhan 430079, Hubei, Peoples R China
关键词
PHOTOREDOX;
D O I
10.1039/d0qo00460j
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
New photoinduced strategies towards radical reactions of strained molecules such as [1.1.1]propellane and bicyclo[1.1.0]butanes by photoredox or metallaphotoredox catalysis have recently been disclosed. Such strategies enable the controllable construction of 1,3-difunctionalized bicyclo[1.1.1]pentanes, cyclobutanes, and drug-like analogues, and offer new opportunities for reaction design of [1.1.1]propellane and other strained molecules.
引用
收藏
页码:2531 / 2537
页数:7
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