Copper(0)-catalyzed aerobic oxidative synthesis of imines from amines under solvent-free conditions

被引：72

作者：

Patil, Rajendra D. ^{[1
]}

Adimurthy, Subbarayappa ^{[1
]}

机构：

[1] CSIR, Cent Salt & Marine Chem Res Inst, Analyt Sci Div, Bhavnagar 364021, Gujarat, India

来源：

RSC ADVANCES | 2012年 / 2卷 / 12期

关键词：

SECONDARY-AMINES; BENZYLIC AMINES; ALCOHOLS; DEHYDROGENATION; BENZYLAMINES; ALKYLATION; CATALYST; AMIDES; GOLD;

D O I：

10.1039/c2ra20339a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A copper(0)-catalyzed direct synthesis of imines from amines under solvent-free aerobic conditions is described. The method is applicable for the synthesis of various imines from corresponding amines such as benzylic, aliphatic, cyclic secondary and heteroaromatic amines. Being solvent free, using air as a benign oxidant, and the easy separation and easy availability of the catalyst (copper powder) are the vital advantages of present protocol.

引用

页码：5119 / 5122

页数：4

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