Temperature dependence of surface tension of 2-methyl-1-propanol and 2-methyl-2-propanol+n-hexane mixtures

被引:8
|
作者
Giner, Beatriz [1 ]
Bandres, Isabel [1 ]
Giner, Ignacio [1 ]
Montano, Diego F. [1 ]
Lopez, M. Carmen [1 ]
机构
[1] Univ Zaragoza, Dept Quim Organ Quim Fis, Fac Ciencias, Zaragoza, Spain
关键词
surface tension; surface formation; 2-methyl-1-propanol; 2-methyl-2-propanol; n-hexane;
D O I
10.1080/00319100802126528
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Surface tensions of binary mixtures of 2-methyl-1-propanol or 2-methyl-2-propanol with n-hexane have been measured in the temperature range 283.15 K-313.15 K for mixtures containing 2-methyl-1-propanol and from 298.15 K to 313.15 K for mixtures formed by 2-methyl-2-propanol, with a drop volume tensiometer. The corresponding surface tension deviations have been calculated and correlated. Using the temperature dependence of surface tensions, the entropy and enthalpy of surface formation per unit area were evaluated at the studied temperatures.
引用
收藏
页码:643 / 652
页数:10
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