Vanadium nitride functionalization and denitrogenation by carbon disulfide and dioxide

被引：39

作者：

Brask, JK ^{[1
]}

Durà-Vilà, V ^{[1
]}

Diaconescu, PL ^{[1
]}

Cummins, CC ^{[1
]}

机构：

[1] MIT, Dept Chem, Cambridge, MA 02139 USA

来源：

CHEMICAL COMMUNICATIONS | 2002年 / 08期

关键词：

D O I：

10.1039/b111550m

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A dramatic difference in behavior is observed for the dithiocarbamate and carbamate complexes [Ar(Bu-t)N](3)V(NCE2)Na(THF)(2) (E = S or O, respectively), prepared from the corresponding nitride species {[Ar(Bu-t)N](3) V equivalent to NNa}(2) by way of a nucleophilic addition reaction involving carbon disulfide or dioxide, and is rationalized with the aid of DFT calculations.

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页码：902 / 903

页数：2

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