Bis(2,2′-bipyridine-κ2N,N′)(nitrato-κO)copper(II) hexafluorophosphate

被引：2

作者：

Beobide, Garikoitz ^{[1
]}

Castillo, Oscar ^{[1
]}

Garcia-Couceiro, Urko ^{[1
]}

Garcia-Teran, Juan P. ^{[1
]}

Luque, Antonio ^{[1
]}

机构：

[1] Univ Basque Country, Fac Ciencia & Tecnol, Dept Quim Inorgan, E-48080 Bilbao, Spain

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2006年 / 62卷

关键词：

D O I：

10.1107/s1600536806018083

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The title compound, [Cu(NO3)(C10H8N2)(2)]PF6, comprises [Cu(NO3)(bpy)(2)](+) complex cations (bpy = 2,2'-bipyridine) and uncoordinated PF6- anions. The Cu-II ion is five-coordinated in a distorted trigonal bipyramidal fashion by two bpy mol-ecules and one nitrate anion, which is coordinated in an equatorial position through one O atom at a distance of 2.148 (3)angstrom. The two axial Cu-N distances are similar (mean = 1.98 angstrom) and are slightly shorter than the two equatorial Cu-N bonds (mean = 2.06 angstrom). Longer CucO inter-actions exist between complexes, linking them into polymeric chains.

引用

页码：M1353 / M1355

页数：3

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