The Rise of Hydrogen Peroxide as the Main Product by Metal-Free Catalysis in Oxygen Reductions

被引：306
作者：
Melchionna, Michele [1 ]
Fornasiero, Paolo [1 ,2 ]
Prato, Maurizio [1 ,3 ,4 ]
机构：
[1] Univ Trieste, INSTM, Dept Chem & Pharmaceut Sci, Via L Giorgieri 1, I-34127 Trieste, Italy
[2] Univ Trieste, ICCOM CNR, Via L Giorgieri 1, I-34127 Trieste, Italy
[3] CIC biomaGUNE, Carbon Nanobiotechnol Lab, Paseo Miramon 182, Donostia San Sebastian 20009, Spain
[4] Ikerbasque, Basque Fdn Sci, Bilbao 48013, Spain
来源：
ADVANCED MATERIALS | 2019年 / 31卷 / 13期
关键词：
carbon nanoforms; hydrogen peroxide; metal-free catalysis; oxygen reduction reaction; DOPED CARBON; H2O2; ELECTROCATALYSIS; PALLADIUM; GOLD;
D O I：
10.1002/adma.201802920
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
One of the recent trends in electrocatalytic reactions involves the oxygen reduction reaction (ORR), where a new paradigm has been shaped to exploit this reaction for the synthesis of hydrogen peroxide (H2O2). H2O2 is a very versatile chemical of high commercial value, prepared currently through poorly sustainable processes. The emergence of metal-free carbon catalysts for the selective synthesis of H2O2 is expected to revolutionize ORR research, beckoning at the development of new industrial schemes. The complexities of the mechanism and the factors dominating the selectivity of the process have been unveiled through a combination of theoretical and experimental studies.
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页数：5
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