Synthesis and structure of the three-dimensional coordination polymer [Ag3hmt3(μ3-btc)]•5H2O

被引：0
作者：
Qin, SB
Lu, SM
Ke, YX
Li, JM [1 ]
Zhou, SX
Wu, XT
Du, WX
机构：
[1] Univ Sci & Technol China, Dept Chem Phys, Hefei 230026, Anhui, Peoples R China
[2] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China
来源：
CRYSTAL RESEARCH AND TECHNOLOGY | 2006年 / 41卷 / 01期
关键词：
crystal structure; Ag-hmt complexes; hydrogen bond; three-dimensional network;
D O I：
10.1002/crat.200310537
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
A new coordination polymer, [Ag(3)hmt(3)(mu(3)-btc)]center dot 5H(2)O (1) (hint = hexamethylenetetramine, btc=1,3,5-benzenetricarboxlic), has been successfully synthesized. Crystal data: P2(1)/a, a 11.9906(2) angstrom, b = 17.3689(2) angstrom, c = 16.96100(10) angstrom, beta = 101.9820(14)degrees, V = 3455.40(7) angstrom(3), Z = 4, Dc 2.002 Mg/m(3). In the hexagonal structure of Ag-hmt unit, each Ag-hmt unit comprises three Ag atoms and three hint ligands. The mu(3)-btc ligands bridge adjacent two-dimensional honeycomb-like Ag-hmt layers to form three-dimensional networks. Structure analysis show that hydrogen bonds play a key role for the stable structure in the compounds.
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页码：98 / 102
页数：5
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