In situ trace elements and Sr isotopes in scheelite and S-Pb isotopes in sulfides from the Shiweidong W-Cu deposit, giant Dahutang ore field: Implications to the fluid evolution and ore genesis

被引:23
作者
Cao Jingya [1 ,2 ]
Yang Xiaoyong [2 ]
Zhang Dexian [3 ]
Yan Fabao [4 ]
机构
[1] Geol Survey Anhui Prov, Hefei 230001, Peoples R China
[2] Univ Sci & Technol China, CAS Key Lab Crust Mantle Mat & Environm, Hefei 230026, Peoples R China
[3] Cent South Univ, Key Lab Metallogen Predict Nonferrous Met & Geol, Minist Educ, Changsha 410083, Peoples R China
[4] Shandong Univ, Inst Space Sci, Weihai 264209, Peoples R China
基金
中国国家自然科学基金; 国家重点研发计划;
关键词
In-situ LA-MC-ICP-MS analyses; Trace element compositions of scheelite; Sr-Pb-S isotopes; Fluid evolution; Shiweidong tungsten deposit; South China; MOLYBDENITE RE-OS; TUNGSTEN POLYMETALLIC DEPOSIT; LA-ICP-MS; NORTHERN JIANGXI PROVINCE; CENTRAL NANLING DISTRICT; SOUTHERN ANHUI PROVINCE; CHINA IMPLICATIONS; OROGENIC BELT; SKARN DEPOSIT; GOLD DEPOSITS;
D O I
10.1016/j.oregeorev.2020.103696
中图分类号
P5 [地质学];
学科分类号
0709 ; 081803 ;
摘要
The Shiweidong W-Cu polymetallic deposit, with resources of 300,000 t WO3 and 200,000 t Cu, is one of the major tungsten polymetallic deposits in the giant Dahutang ore field. This study conducted a series of in-situ analyses on scheelite and sulfides, aiming to provide some new insights into the sources, hydrothermal ore-forming processes, fluid evolution history and genesis of this deposit, which is of importance to understand the formation of the super-large Dahutang ore field. Quartz vein- and veinlet-disseminated-type tungsten ore bodies are mainly hosted in Neoproterozoic granodiorite and/or the Yanshanian porphyritic two-mica granites. Four stages of mineralization from early to late are identified in this deposit: 1) pegmatite stage; 2) silicate-oxide stage; 3) oxide-sulfide stage; and 4) sulfide stage. The delta S-34(v)-(CDT) values of stage 3 chalcopyrite and pyrite are from -1.73 parts per thousand to -1.46 parts per thousand and from -1.66 parts per thousand to -0.31 parts per thousand, respectively, indicating a magma-related hydro thermal origin. The (206)pb/(204)pb, (2067)pb/(204)pb and Pb-208/Pb-204 ratios pyrite range from 18.169 to 18.295, 15.650 to 15.679, and 38.496 to 38.525, respectively, revealing a crust origin for the Pb. Trace element compositions of scheelite show that the both stage 2 scheelite (scheelite-II) and stage 3 scheelite (scheelite-III) have high contents of Nb and REEs. The scheelite-II has a narrow range of the Y/Ho ratios (16.2-31.0), obviously negative Eu anomalies (Eu/Eu* = 0.04-0.46) and relatively low Sr-87/Sr-86 ratios of 0.72640-0.73336, whereas scheelite-III shows variable Y/Ho ratios of 20.6-96.9, positive Eu anomalies (Eu/Eu* = 1.31-7.11) and relatively high Sr-87/Sr-86 ratios of 0.73496-0.76098. These data indicated that the Eu anomalies and Sr isotopic compositions of scheelite-II were inherited from magmatic-hydrothermal fluids, whereas those of scheelite-III were sourced from modified fluids due to intense fluid-rock interaction and input of meteoric fluids. Our data also reveal that the REEs of scheelite-II and scheelite-III are mainly controlled by the substitution mechanism of 3Ca(2) = square Ca + 2REE(3+). The W-rich reduced fluids and intense fluid-rock interactions, which could provide enough W and Ca, are likely the key factors for the formation of scheelite in the Shiweidong tungsten deposit.
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页数:14
相关论文
共 104 条
[1]   Development of pressed sulfide powder tablets for in situ sulfur and lead isotope measurement using LA-MC-ICP-MS [J].
Bao, Zhian ;
Chen, Lu ;
Zong, Chunlei ;
Yuan, Honglin ;
Chen, Kaiyun ;
Dai, Mengning .
INTERNATIONAL JOURNAL OF MASS SPECTROMETRY, 2017, 421 :255-262
[2]   Tracing element sources of hydrothermal mineral deposits:: REE and Y distribution and Sr-Nd-Pb isotopes in fluorite from MVT deposits in the Pennine Orefield, England [J].
Bau, M ;
Romer, RL ;
Lüders, V ;
Dulski, P .
MINERALIUM DEPOSITA, 2003, 38 (08) :992-1008
[3]   RARE-EARTH ELEMENT FRACTIONATION IN METAMORPHOGENIC HYDROTHERMAL CALCITE, MAGNESITE AND SIDERITE [J].
BAU, M ;
MOLLER, P .
MINERALOGY AND PETROLOGY, 1992, 45 (3-4) :231-246
[4]  
BELL K, 1989, GEOLOGY, V17, P500, DOI 10.1130/0091-7613(1989)017<0500:SNARSI>2.3.CO
[5]  
2
[6]   Isotopic compositions of the elements 2009 (IUPAC Technical Report) [J].
Berglund, Michael ;
Wieser, Michael E. .
PURE AND APPLIED CHEMISTRY, 2011, 83 (02) :397-410
[7]   Inhomogeneous distribution of REE in scheelite and dynamics of Archaean hydrothermal systems (Mt. Charlotte and Drysdale gold deposits, Western Australia) [J].
Brugger, J ;
Lahaye, Y ;
Costa, S ;
Lambert, D ;
Bateman, R .
CONTRIBUTIONS TO MINERALOGY AND PETROLOGY, 2000, 139 (03) :251-264
[8]   Origins of Nd-Sr-Pb isotopic variations in single scheelite grains from Archaean gold deposits, Western Australia [J].
Brugger, J ;
Maas, R ;
Lahaye, Y ;
McRae, C ;
Ghaderi, M ;
Costa, S ;
Lambert, D ;
Bateman, R ;
Prince, K .
CHEMICAL GEOLOGY, 2002, 182 (2-4) :203-225
[9]   Oxidation state of europium in scheelite: Tracking fluid-rock interaction in gold deposits [J].
Brugger, Joel ;
Etschmann, Barbara ;
Pownceby, Mark ;
Liu, Weihua ;
Grundler, Pascal ;
Brewe, Dale .
CHEMICAL GEOLOGY, 2008, 257 (1-2) :26-33
[10]  
Cai Y, 2012, ACTA PETROL SIN, V28, P3798