Single-phased CaAl2Si2O8:Tm3+, Dy3+ white-light phosphors under ultraviolet excitation

被引:43
|
作者
Yang, Penghui [1 ]
Yu, Xue [1 ,2 ]
Xu, Xuhui [1 ]
Jiang, Tingming [1 ]
Yu, Hongling [1 ]
Zhou, Dacheng [1 ,2 ]
Yang, Zhengwen [1 ,2 ]
Song, Zhiguo [1 ,2 ]
Qiu, Jianbei [1 ,2 ]
机构
[1] Kunming Univ Sci & Technol, Coll Mat Sci & Engn, Kunming 650093, Peoples R China
[2] Kunming Univ Sci & Technol, Coll Mat Sci & Engn, Key Lab Adv Mat Yunnan Prov, Kunming 650093, Peoples R China
基金
中国国家自然科学基金; 高等学校博士学科点专项科研基金;
关键词
Energy transfer; White LED; CaAl2Si2O8; Tm3+ and Dy3+; ENERGY-TRANSFER MECHANISM; LUMINESCENCE; GENERATION; EU2+; CE3+; MN2+;
D O I
10.1016/j.jssc.2013.03.017
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A novel white-light-emitting phosphor CaAl2Si2O8:Tm, Dy was synthesized in ambient atmosphere by solid-state reaction. The energy transfer from Tm3+ to Dy3+ ions via a dipole-quadrupole reaction was observed and investigated. Upon UV excitation, white light emission was achieved by integrating a blue emission band located at 455 nm and an orange one located at 574 nm attributed to Tm3+ and Dy3+ ions, respectively. In addition, the energy-transfer efficiency and critical distance were calculated. Results suggested that the phosphor might be promising as a single-phased white-light-emitting phosphor for UV white-light LED. (C) 2013 Elsevier Inc. All rights reserved.
引用
收藏
页码:143 / 148
页数:6
相关论文
共 50 条
  • [41] Synthesis of novel Dy3+ activated Ba2CaZn2Si6O17 phosphors for white light-emitting diodes
    Annadurai, G.
    Kennedy, S. Masilla Moses
    Sivakumar, V.
    LUMINESCENCE, 2018, 33 (03) : 521 - 527
  • [42] Hydrothermal Preparation and Luminescence Properties of NaGd (MoO4)2 : Dy3+, Eu3+ White-light Phosphors
    Jiang Ying-Ying
    Liu Gui-Xia
    Wang Jin-Xian
    Dong Xiang-Ting
    Yu Wen-Sheng
    CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE, 2013, 34 (04): : 794 - 799
  • [43] Tm3+/Dy3+ co-doped BaO-B2O3-P2O5-Na2O glass and NaBaPO4 glass-ceramic for white LED
    Tang, Jian
    Dong, Xingui
    Xing, Junhao
    Tang, Yongfeng
    Qin, Lina
    Shang, Fei
    Chen, Guohua
    OPTICAL MATERIALS, 2022, 133
  • [44] Insight into the synthesis and luminescence properties of the single-ion-activated single-phased Na3ScSi2O7:Dy3+ phosphor for white light-emitting diodes
    Wei, Chao
    Xu, Denghui
    Yang, Zaifa
    Li, Jinling
    Chen, Xiaobai
    Li, Xiong
    Sun, Jiayue
    APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING, 2019, 125 (06):
  • [45] Warm white light generation from single phase Sr3Y(PO4)3:Dy3+, Eu3+ phosphors with near ultraviolet excitation
    Huang, B. Y.
    Feng, B. L.
    Luo, L.
    Han, C. L.
    He, Y. T.
    Qiu, Z. R.
    MATERIALS SCIENCE AND ENGINEERING B-ADVANCED FUNCTIONAL SOLID-STATE MATERIALS, 2016, 212 : 71 - 77
  • [46] Effective energy transfer between Ce3+ and Eu2+ in CaAl2Si2O8 host under vacuum ultraviolet illumination
    Jung, Kyeong Youl
    Kim, Joo Hyun
    JOURNAL OF LUMINESCENCE, 2008, 128 (12) : 2004 - 2007
  • [47] A novel white-light emitting BaBi2Nb2O9: Li+/Tm3+/Er3+/Yb3+ upconversion phosphor
    Facanha, Marcello X.
    do Carmo, Felipe F.
    do Nascimento, Joao P. C.
    Sales, Tasso O.
    Santos, Weslley Q.
    Gouveia-Neto, Artur S.
    da Silva, Carlos J.
    Sombra, Antonio S. B.
    JOURNAL OF LUMINESCENCE, 2018, 204 : 539 - 547
  • [48] Ca3La2W2O12:aTm3+, bDy3+: A potential tunable single-phased white-emitting phosphor under near-ultraviolet light excitation
    Fu, Hao
    Ren, Qiang
    Wu, Xiulan
    Pei, Mengkang
    Hai, Ou
    JOURNAL OF LUMINESCENCE, 2022, 252
  • [49] Luminescence, energy transfer and color perception studies of Na3Gd(PO4)2:Dy3+:Tm3+ phosphors
    Jamalaiah, B. C.
    Jo, Misun
    Zehan, Jiang
    Shim, Jae Jeong
    Kim, Sun Il
    Chung, Wan-Young
    Seo, Hyo Jin
    OPTICAL MATERIALS, 2014, 36 (10) : 1688 - 1693
  • [50] Development of a single-phased Ca3SnSi2O9: Bi3+, Dy3+, Eu3+ phosphor with tri-colors for white light-emitting diodes
    Yu, Xue
    Zhang, Lei
    Xu, Xuhui
    Wang, Ting
    Yu, Hongling
    Jiang, Tingming
    Jiao, Qing
    Yang, Zhengwen
    Zhou, Dacheng
    Qiu, Jianbei
    JOURNAL OF LUMINESCENCE, 2014, 145 : 114 - 118