Low temperature heat capacity and thermodynamic parameters of phase transitions of 4-nitro-4′-tert-butyl-diphenyl oxide

被引：3
|
作者：
Druzhinina, A. I. [1 ]
Pimenova, S. M. [1 ]
Lukyanova, V. A. [1 ]
机构：
[1] Lomonosov State Univ Moscow, Dept Chem, Moscow 119991, Russia
来源：
JOURNAL OF CHEMICAL THERMODYNAMICS | 2017年 / 105卷
关键词：
Adiabatic calorimetry; Heat capacity; Thermodynamic functions; Entropy of formation; 4-nitro-4 '-tert-butyl-diphenyl oxide; IUPAC TECHNICAL REPORT; BIPHENYL DERIVATIVES; DIPHENYL ETHER; ATOMIC WEIGHTS;
D O I：
10.1016/j.jct.2016.10.031
中图分类号：
O414.1 [热力学];
学科分类号：
摘要：
The low-temperature heat capacity of 4-nitro-4'-tert-butyl-diphenyl oxide was measured by vacuum adiabatic calorimetry over the temperature range (7-372) K. The temperature, the enthalpy and the entropy of fusion and the temperature, the jump of the heat capacity, and the range of devitrification of the glass transition were determined. Heat capacity and main thermodynamic functions (changes of entropy, enthalpy, and Gibbs energy) in condensed state are tabulated as a function of temperature from 5 K to 370 K. The entropy of formation at T = 298.15 K of 4-nitro-4'-tert-butyl-diphenyl oxide in the crystal state was computed on the basis of the experimental results obtained. (C) 2016 Elsevier Ltd.
引用
收藏
页码：312 / 316
页数：5
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