Sorption of Cd2+ ions onto zeolite synthesized from perlite waste

被引:8
作者
Krol, M. [1 ]
Matras, E. [1 ]
Mozgawa, W. [1 ]
机构
[1] AGH Univ Sci & Technol, Fac Mat Sci & Ceram, 30 Mickiewicza Ave, PL-30059 Krakow, Poland
关键词
Zeolite X; Cadmium; Expanded perlite; Sorption; LOW-TEMPERATURE SYNTHESIS; HEAVY-METAL REMOVAL; COAL FLY-ASH; AQUEOUS-SOLUTIONS; ACTIVATED CARBON; ADSORPTION; CLINOPTILOLITE; CADMIUM; EXCHANGE; PRODUCTS;
D O I
10.1007/s13762-016-1098-9
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
In this work, the studies on the formation of zeolites from expanded perlite waste and their use in the sorption process of Cd2+ ions will be reported. Such approach is innovative and has not been investigated elsewhere. The results of the synthesis of zeolites from aluminosilicate waste using hydrothermal method were presented. By-product from the process production of expanded perlite was used as the starting material. Theoretical and practical aspects of Cd2+ ions sorption process onto material synthesized in selected conditions (a material with good sorption capacity can be obtained by 24 h reaction of 1 g of perlite waste in 10 mL of 4.0 M NaOH solution with at 70 A degrees C) will be presented. The atomic absorption spectroscopy has been used as the main method, from which the effective cation exchange capacity as well as the proportion of ion exchange to chemisorption in the sorption process have been determined. Structural analyses of the sample before and after sorption process have been also carried out by the mid-infrared spectra measurement, especially pseudolattice range of the spectra was analyzed in detail in which changes caused by ion exchange of non-tetrahedral ions have been observed.
引用
收藏
页码:2697 / 2704
页数:8
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