Ca2(H3O)2[V10O28]•16H2O

被引：15

作者：

Strukan, N ^{[1
]}

Cindric, M ^{[1
]}

Kamenar, B ^{[1
]}

机构：

[1] Univ Zagreb, Fac Sci, Lab Gen & Inorgan Chem, Zagreb 10000, Croatia

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1999年 / 55卷

关键词：

D O I：

10.1107/S0108270198013468

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The crystal structure of dicalcium bis(oxonium) decavanadate hexadecahydrate has been determined by X-ray analysis, The main feature of the structure is the [V10O28](6-) anion, built up from ten distorted edge-sharing VO6 octahedra with well established structures. Each Ca2+ ion is surrounded by seven water molecules in the form of a distorted pentagonal bipyramid, Water H atoms, as well as those of the H3O+ ions, participate in a complicated three-dimensional hydrogen-bonding system.

引用

页码：291 / 293

页数：3

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