Graphene oxide-decorated Fe2(MoO4)3 microflowers as a promising anode for lithium and sodium storage

被引:27
|
作者
Han, Chunhua [1 ]
Ren, Xiaoji [1 ]
Li, Qidong [1 ]
Luo, Wen [1 ,2 ]
Huang, Lei [1 ]
Zhou, Liang [1 ]
Mai, Liqiang [1 ,3 ]
机构
[1] Wuhan Univ Technol, State Key Lab Adv Technol Mat Synth & Proc, Luoshi Rd 122, Wuhan 430070, Hubei, Peoples R China
[2] Univ Lorraine, Inst Jean Barriol, Lab Chim & Phys Approche Multiechelles Milieux Co, F-57070 Metz, France
[3] Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA
基金
中国国家自然科学基金;
关键词
Fe-2(MoO4)(3) microflowers; anode; lithium and sodium storage; ELECTROCHEMICAL ENERGY-STORAGE; ION BATTERIES; HOLLOW MICROSPHERES; SUPERIOR LITHIUM; XPS SPECTRA; PERFORMANCE; NANOPARTICLES; CAPACITY; COMPOSITE; MECHANISM;
D O I
10.1007/s12274-017-1742-9
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Mixed transition metal oxides (MTMOs) have received intensive attention as promising anode materials for lithium-ion batteries (LIBs) and sodium-ion batteries (SIBs). In this work, we demonstrate a facile one-step water-bath method for the preparation of graphene oxide (GO) decorated Fe-2(MoO4)(3) (FMO) microflower composite (FMO/GO), in which the FMO is constructed by numerous nanosheets. The resulting FMO/GO exhibits excellent electrochemical performances in both LIBs and SIBs. As the anode material for LIBs, the FMO/GO delivers a high capacity of 1,220 mAh.g(-1) at 200 mA.g(-1) after 50 cycles and a capacity of 685 mAh.g(-1) at a high current density of 10 A.g(-1). As the anode material for SIBs, the FMO/GO shows an initial discharge capacity of 571 mAh.g(-1) at 100 mA.g(-1), maintaining a discharge capacity of 307 mAh.g(-1) after 100 cycles. The promising performance is attributed to the good electrical transport from the intimate contact between FMO and graphene oxide. This work indicates that the FMO/GO composite is a promising anode for high-performance lithium and sodium storage.
引用
收藏
页码:1285 / 1293
页数:9
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