Activity of commercial zeolites with iron impurities in direct N2O decomposition

被引：39
|
作者：
Oygarden, Arne H.
Perez-Ramirez, Javier
机构：
[1] ICREA, Tarragona 43007, Spain
[2] Inst Chem Res Catalonia ICIQ, Tarragona 43007, Spain
[3] Yara Technol Ctr Porsgrunn, N-3908 Porsgrunn, Norway
来源：
APPLIED CATALYSIS B-ENVIRONMENTAL | 2006年 / 65卷 / 1-2期
关键词：
zeolites; framework type; N2O decomposition; iron impurities; steaming;
D O I：
10.1016/j.apcatb.2006.03.002
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Various commercially available zeolite frameworks (MFI, FER, BEA, MOR, FAU) with iron impurities ranging from 85 to 780 ppm and nominal Si/Al ratios of 10-15 have been tested in direct N2O decomposition after calcination and steam treatment. Our results show a significant impact of the framework type on the catalytic activity at these high degrees of iron dilution (Fe/Al < 0.01). H-beta was the most effective material in the reaction, followed by the other pentasyl-type H-ferrierite and H-ZSM-5 zeolites. (c) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码：163 / 167
页数：5
相关论文
共 50 条
  • [31] DFT Study on Mechanisms of the N2O Direct Catalytic Decomposition over Cu-ZSM-5: The Detailed Investigation on NO Formation Mechanism
    Gao, Congru
    Li, Jianwei
    Zhang, Jie
    Sun, Xiuliang
    CATALYSTS, 2020, 10 (06)
  • [32] Catalytic Decomposition of N2O in the Presence of O2throughRedox of Rh Oxide in a RhOx/ZrO2Catalyst
    Jing, Yuan
    Taketoshi, Koichiro
    Zhang, Ningqiang
    He, Chenxi
    Toyao, Takashi
    Maeno, Zen
    Ohori, Teppei
    Ishikawa, Naoya
    Shimizu, Ken-ichi
    ACS CATALYSIS, 2022, 12 (11) : 6325 - 6333
  • [33] Ordered mesoporous CuO-CeO2 mixed oxides as an effective catalyst for N2O decomposition
    Zabilskiy, Maxim
    Erjavec, Bostjan
    Djinovic, Petar
    Pintar, Albin
    CHEMICAL ENGINEERING JOURNAL, 2014, 254 : 153 - 162
  • [34] Unravelling the Effect of Alkali Metal Deposition on Co3O4 for Catalytic Decomposition of N2O
    Sun, Jinru
    Song, Aolei
    Tian, Yu
    Zhan, Hua
    Deng, Jianlin
    Wang, Hong
    Ke, Ming
    CHEMCATCHEM, 2023, 15 (05)
  • [35] Small CuO clusters on CeO2 nanospheres as active species for catalytic N2O decomposition
    Zabilskiy, Maxim
    Djinovic, Petar
    Erjavec, Bostjan
    Drazic, Goran
    Pintar, Albin
    APPLIED CATALYSIS B-ENVIRONMENTAL, 2015, 163 : 113 - 122
  • [36] In-situ DRIFTS study of CeO2 supported Rh catalysts for N2O decomposition
    Zhu, Haiyang
    Li, Yuejin
    Zheng, Xiaolai
    APPLIED CATALYSIS A-GENERAL, 2019, 571 : 89 - 95
  • [37] Control of metal ion species in zeolites by distribution of aluminium in the framework: From structural analysis to performance under real conditions of SCR-NOx and NO, N2O decomposition
    Dedecek, J.
    Capek, L.
    Sazama, P.
    Sobalik, Z.
    Wichterlova, B.
    APPLIED CATALYSIS A-GENERAL, 2011, 391 (1-2) : 244 - 253
  • [38] Effect of the crystal size of Cu-ZSM-5 on the catalytic performance in N2O decomposition
    Meng, Tao
    Lin, Yi
    Ma, Zhen
    MATERIALS CHEMISTRY AND PHYSICS, 2015, 163 : 293 - 300
  • [39] Oxydehydrogenation of C2-C4 hydrocarbons over Fe-ZSM-5 zeolites with N2O as an oxidant
    Kowalska-Kus, Jolanta
    Held, Agnieszka
    Nowinska, Krystyna
    CATALYSIS SCIENCE & TECHNOLOGY, 2013, 3 (02) : 508 - 518
  • [40] Decomposition of N2O by Ruthenium Catalysts - RuO2 as Active Phase on Non-Reducible Supports
    Zhang, Xiaoqiao
    Zheng, Jian
    Boch, Florian Johannes
    Nickl, Simon
    Koehler, Klaus
    CHEMCATCHEM, 2024, 16 (22)
12345