One-pot direct C-H arylation of arenes in water catalysed by RuCl3•nH2O-NaOAc in the presence of Zn

被引：32

作者：

Adrio, Luis A. ^{[1
]}

Gimeno, Jose ^{[1
]}

Vicent, Cristian ^{[2
]}

机构：

[1] Univ Oviedo, Inst Univ Quim Organomet Enrique Moles, Dept Quim Organ & Inorgan, Lab Quim Organomet & Catalisis,Unidad Asociada CS, E-33071 Oviedo, Spain

[2] Univ Jaume 1, Serv Cent Instrumentacio Cient, Castellon de La Plana 12071, Spain

来源：

CHEMICAL COMMUNICATIONS | 2013年 / 49卷 / 75期

关键词：

IONIZATION MASS-SPECTROMETRY; BOND ACTIVATION; ARYL CHLORIDES; FUNCTIONALIZATION; COMPLEXES; ELECTROPHILES; CARBONATE; MECHANISM; OXIDATION; ACETATE;

D O I：

10.1039/c3cc43452d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The inexpensive and commercially available catalytic system RuCl3 center dot nH(2)O-NaOAc-Zn is active in water for the direct C-H arylation of arenes with aryl/heteroaryl chlorides. The reaction can be accelerated by the use of microwave irradiation and can also be scaled up to a multi-gram scale with excellent isolated yields.

引用

收藏

页码：8320 / 8322

页数：3

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