Mechanical and thermo-physical properties of high-density polyethylene modified with talc

被引:25
作者
Mehrjerdi, Adib Kalantar [1 ]
Adl-Zarrabi, Bijan [2 ]
Cho, Sung-Woo [1 ]
Skrifvars, Mikael [1 ]
机构
[1] Univ Boras, Sch Engn, SE-50190 Boras, Sweden
[2] Chalmers Univ Technol, SE-41296 Gothenburg, Sweden
关键词
polyolefins; thermal properties; blends; composites; differential scanning calorimetry; CARBON-BLACK; CONDUCTIVITY; POLYPROPYLENE; DEGRADATION; COMPOSITES; POLYMERS; CRYSTALLIZATION; DECOMPOSITION; ORIENTATION;
D O I
10.1002/app.38945
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The aim of this study was to examine the physical, mechanical, and thermo-physical properties of high-density polyethylene (HDPE) modified with talc. Different weight fractions of talc (up to 35 wt %) were compounded with an HDPE matrix containing 2.5 wt % of carbon black (CB) in a twin-screw compounder. The composites were then processed by injection moulding to obtain specimens for testing. The results indicate that CB causes a significant decrease in the toughness, while talc not only enhances the thermal conductivity and thermo-physical properties of the composites but can also play a role in compensating for the negative effects of CB on impact resistance. The experimental data show that the presence of CB reduces the impact resistance of HDPE by up to 34%, while addition of up to 8 wt % talc can return this value to close to that of pure HDPE. No significant effect on the composite tensile yield and fracture strength was observed for either component at all concentrations. The thermal conductivity, thermal diffusivity, and specific density values of the composites increased almost linearly, but the increase in moisture absorption in the long term showed nonlinear behavior in the concentration range of the experiment. (c) 2013 Wiley Periodicals, Inc. J. Appl. Polym. Sci., 2013
引用
收藏
页码:2128 / 2138
页数:11
相关论文
共 45 条
[1]   Mechanical, flow, and morphological properties of talc- and kaolin-filled polypropylene hybrid composites [J].
Abu Bakar, M. B. ;
Leong, Y. W. ;
Ariffin, A. ;
Ishak, Z. A. Mohd. .
JOURNAL OF APPLIED POLYMER SCIENCE, 2007, 104 (01) :434-441
[2]   THERMAL-CONDUCTIVITY OF POLYMER FILLED WITH CARBON MATERIALS - EFFECT OF CONDUCTIVE PARTICLE CHAINS ON THERMAL-CONDUCTIVITY [J].
AGARI, Y ;
UNO, T .
JOURNAL OF APPLIED POLYMER SCIENCE, 1985, 30 (05) :2225-2235
[3]   FILLER PARTICLE SIZE AND MECHANICAL PROPERTIES OF POLYMERS [J].
ALTER, H .
JOURNAL OF APPLIED POLYMER SCIENCE, 1965, 9 (04) :1525-&
[4]   Degradation studies of polyolefins incorporating transparent nanoparticulate zinc oxide UV stabilizers [J].
Ammala, A ;
Hill, AJ ;
Meakin, P ;
Pas, SJ ;
Turney, TW .
JOURNAL OF NANOPARTICLE RESEARCH, 2002, 4 (1-2) :167-174
[5]   Outdoor and accelerated weathering tests for polypropylene and polypropylene/talc composites: A comparative study of their weathering behavior [J].
Azuma, Y. ;
Takeda, H. ;
Watanabe, S. ;
Nakatani, H. .
POLYMER DEGRADATION AND STABILITY, 2009, 94 (12) :2267-2274
[6]   MECHANICAL, THERMAL, AND ELECTRICAL-PROPERTIES OF METAL FIBER-FILLED POLYMER COMPOSITES [J].
BIGG, DM .
POLYMER ENGINEERING AND SCIENCE, 1979, 19 (16) :1188-1192
[7]  
BIGG DM, 1995, ADV POLYM SCI, V119, P1
[8]   THE EFFECTS OF PIGMENTS ON THE PHOTOSTABILITY OF POLYETHYLENE [J].
BIGGER, SW ;
DELATYCKI, O .
JOURNAL OF MATERIALS SCIENCE, 1989, 24 (06) :1946-1952
[9]   FACTORS AFFECTING THE MECHANICAL-PROPERTIES OF MICA-FILLED POLYPROPYLENES [J].
BUSIGIN, C ;
MARTINEZ, GM ;
WOODHAMS, RT ;
LAHTINEN, R .
POLYMER ENGINEERING AND SCIENCE, 1983, 23 (14) :766-770
[10]   Effects of talc orientation and non-isothermal crystallization rate on crystal orientation of polypropylene in injection-molded polypropylene/ethylene-propylene rubber/talc blends [J].
Choi, WJ ;
Kim, SC .
POLYMER, 2004, 45 (07) :2393-2401