Transesterification of β-ketoesters with alcohols catalyzed by montmorillonite K-10

被引:37
作者
Jin, TS [1 ]
Zhang, SL [1 ]
Li, TS [1 ]
机构
[1] Hebei Univ, Dept Chem, Baoding 071002, Hebei Province, Peoples R China
关键词
D O I
10.1039/b109439b
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Montmorillonite K-10 is an efficient reusable catalyst for the transesterification of ethyl/methyl beta-ketoester; with various alcohols in good yields. The main advantages of the catalyst are easy operation in the workup and a more economical and environmentally benign procedure.
引用
收藏
页码:32 / 34
页数:3
相关论文
共 21 条
[1]   Simple and high yielding syntheses of β-ketoesters catalysed by zeolites [J].
Balaji, BS ;
Chanda, BM .
TETRAHEDRON, 1998, 54 (43) :13237-13252
[2]   Metal salts as novel catalysts for efficient transesterification of β-ketoesters [J].
Bandgar, BP ;
Sadavarte, VS ;
Uppalla, LS .
SYNTHETIC COMMUNICATIONS, 2001, 31 (13) :2063-2066
[3]   Envirocat EPZG and natural clay as efficient catalysts for transesterification of β-keto esters [J].
Bandgar, BP ;
Uppalla, LS ;
Sadavarte, VS .
GREEN CHEMISTRY, 2001, 3 (01) :39-41
[4]  
Campbell D. S., 1971, CHEM COMMUN, P355
[5]   Use of solid superacid (Sulphated SnO2) as efficient catalyst in facile transesterification of ketoesters [J].
Chavan, SP ;
Zubaidha, PK ;
Dantale, SW ;
Keshavaraja, A ;
Ramaswamy, AV ;
Ravindranathan, T .
TETRAHEDRON LETTERS, 1996, 37 (02) :233-236
[6]   KINETIC AND SPECTROSCOPIC STUDIES ON THE THERMAL-DECOMPOSITION OF 2,2,6-TRIMETHYL-4H-1,3-DIOXIN-4-ONE - GENERATION OF ACETYLKETENE [J].
CLEMENS, RJ ;
WITZEMAN, JS .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (06) :2186-2193
[7]   DIKETENE [J].
CLEMENS, RJ .
CHEMICAL REVIEWS, 1986, 86 (02) :241-318
[8]   Enantioselective synthesis of (-)-curcumanolide A using enzymatic transesterification of meso-spirodiol [J].
Fujita, T ;
Tanaka, M ;
Norimine, Y ;
Suemune, H ;
Sakai, K .
JOURNAL OF ORGANIC CHEMISTRY, 1997, 62 (12) :3824-3830
[9]   TRANS-ESTERIFICATION OF 3-OXO ESTERS WITH ALLYLIC ALCOHOLS [J].
GILBERT, JC ;
KELLY, TA .
JOURNAL OF ORGANIC CHEMISTRY, 1988, 53 (02) :449-450
[10]  
GILBERT JS, 1991, J ORG CHEM, V56, P1713