Synthesis and characterization of high coercivity rare-earth ion doped Sr0.9RE0.1Fe10Al2O19 (RE: Y, La, Ce, Pr, Nd, Sm, and Gd)

被引:123
作者
Rai, B. K. [1 ]
Mishra, S. R. [1 ]
Nguyen, V. V. [2 ]
Liu, J. P. [2 ]
机构
[1] Univ Memphis, Dept Phys, Memphis, TN 38152 USA
[2] Univ Texas Arlington, Dept Phys, Arlington, TX 76019 USA
基金
美国国家科学基金会;
关键词
Sr-Ferrite; Autocombustion; Doped ferrite; MAGNETIC-PROPERTIES; DIELECTRIC-PROPERTIES; BARIUM FERRITE; PARTICLE-SIZE; HEXAFERRITE; SUBSTITUTION; ANISOTROPY;
D O I
10.1016/j.jallcom.2012.09.021
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Influence of replacing Sr2+ ions by rare-earth ions (RE3+) ions on the structural and magnetic properties of high coercivity (H-c) SrFe10Al2O19 hexaferrite have been investigated using X-ray diffraction, transmission electron microscopy, differential scanning calorimeter, and SQUID. A 73% increase in intrinsic coercivity is observed for Al3+ doped SrFe10Al2O19 as compared to that of pure SrFe12O19. The RE3+ doping brings in further 50% increase in the coercivity to Sr0.9RE0.1Fe10Al2O19. Overall the Curie temperature of Sr0.9RE0.1Fe10Al2O19 reduced upon RE3+ substitution, however, among rare-earth ions Pr3+ doping showed highest T-c similar to 620 K. Doping SrFe10Al2O19 with RE3+ ions seems to be detrimental to the saturation magnetization but was observed to be favorable to the coercivity enhancement. (C) 2012 Elsevier B.V. All rights reserved.
引用
收藏
页码:198 / 203
页数:6
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