Clay modified carbon paste electrode for the voltammetric detection of dopamine in presence of ascorbic acid

被引:34
作者
Sathisha, Tammanekar V. [1 ]
Swamy, Bahaddurghatta E. Kumara [1 ]
Reddy, Sathish [1 ]
Chandrashekar, Bananakere N. [1 ]
Eswarappa, Bheemappa [2 ]
机构
[1] Kuvempu Univ, Dept PG Studies & Res Ind Chem, Shimoga 577451, Karnataka, India
[2] Sir MV Sci Coll, Dept PG Studies & Res Ind Chem, Shimoga, Karnataka, India
关键词
Alpha cobalt hydroxides; Dopamine; Ascorbic acid; Surfactant; Cyclic voltammetry; SURFACTANTS; HYDROXIDES; SEROTONIN; BROMIDE;
D O I
10.1016/j.molliq.2012.05.005
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
alpha-Cobalt (II) hydroxide (alpha-Co-SO4) was synthesized. Characterized by powder X-ray diffraction, FT-IR spectroscopy, as well as elemental analysis indicates the formation of alpha-cobalt (II) hydroxide. The synthesized alpha-Co (II) hydroxide was used to fabricate modified carbon paste electrode for the determination of dopamine. The alpha-Co-SO4/SDS/CPE was characterized by electrochemical methods and modified electrode was used to determinate dopamine (DA) and ascorbic acid (AA) simultaneously. The detection limit and quantification limits for DA were found to be 2.5 x 10(-7) mol/L and 5.3 x 10(-7) mol/L respectively. (C) 2012 Elsevier B.V. All rights reserved.
引用
收藏
页码:53 / 58
页数:6
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