Synthesis, aggregation and responsivity of block copolymers containing organic arsenicals

被引：12
|
作者：
Tanaka, Joji [1 ]
Tani, Seiji [1 ]
Peltier, Raoul [1 ]
Pilkington, Emily H. [1 ,2 ]
Kerr, Andrew [1 ]
Davis, Thomas P. [1 ,2 ]
Wilson, Paul [1 ,2 ]
机构：
[1] Univ Warwick, Dept Chem, Lib Rd, Coventry CV4 7AL, W Midlands, England
[2] Monash Univ, Monash Inst Pharmaceut Sci, ARC Ctr Excellence Convergent Bionano Sci & Techn, Parkville Campus,399 Royal Parade, Parkville, Vic 3152, Australia
来源：
POLYMER CHEMISTRY | 2018年 / 9卷 / 13期
基金：
英国工程与自然科学研究理事会;
关键词：
LIVING RADICAL POLYMERIZATION; SINGLE-CHAIN NANOPARTICLES; ALTERNATING COPOLYMERIZATION; BIOMEDICAL APPLICATIONS; RAFT POLYMERIZATION; MONOMERS; PH; PHENYLACETYLENE; POLYMERS; CORE;
D O I：
10.1039/c7py01852e
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Block copolymers containing an organic arsenical (AsAm) have been synthesised by aqueous SET-LRP. The block copolymers are pH and thermoresponsive, forming nanoparticles in aqueous solution. Under reductive conditions the particles are stabilised through the formation of As-As bonds and stability can be tuned as a function of the AsAm monomer feed.
引用
收藏
页码：1551 / 1556
页数：6
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