Effect of cation-exchange layer thickness on electrochemical and transport characteristics of bipolar membranes

被引：34

作者：

Zabolotskii, Victor ^{[1
]}

Sheldeshov, Nicolay ^{[1
]}

Melnikov, Stanislav ^{[1
]}

机构：

[1] Kuban State Univ, Krasnodar 350040, Russia

来源：

JOURNAL OF APPLIED ELECTROCHEMISTRY | 2013年 / 43卷 / 11期

基金：

俄罗斯基础研究基金会;

关键词：

Bipolar membrane; Current-voltage characteristic; Electrochemical impedance; Equivalent circuit; Warburg impedance; Gerisher impedance; Transport numbers; Water dissociation; WATER DISSOCIATION; SODIUM-HYDROXIDE; ION LEAKAGE; ACID; ELECTRODIALYSIS; GENERATION; SURFACE; SALT;

D O I：

10.1007/s10800-013-0560-3

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

To study the effect of cation-exchange layer thickness on the electrochemical and transport characteristics of bipolar membranes (BPM), asymmetric BPM with varied cation-exchange layer thickness (of 10, 30, 50 and 70 mu m) were investigated. High influence of BPM monopolar layers thickness on its selectivity had been shown. This fact is non-trivial in relation to monopolar ion-exchange membranes as their selectivity does not depend on their thickness. At the same time, increase or decrease in the thickness of BPM monopolar layers can increase products purity or, on the contrary, combine ion transport and pH shift functions.

引用

页码：1117 / 1129

页数：13

共 50 条

[41] The Correlation between the Water Content and Electrolyte Permeability of Cation-Exchange Membranes
Izquierdo-Gil, M. A.
Villaluenga, J. P. G.
Munoz, S.
Barragan, V. M.
INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES, 2020, 21 (16) : 1 - 11
[42] Kinetics of histidine sorption and desorption on FumasepA® FTCM cation-exchange membranes
Maigurova, N. I.
Eliseeva, T. V.
Lantsuzskaya, E. V.
Sholokhova, A. Yu.
RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A, 2015, 89 (05) : 835 - 839
[43] Influence of polyaniline intercalations on the conductivity and permselectivity of perfluorinated cation-exchange membranes
Compan, V.
Riande, E.
Fernandez-Carretero, F. J.
Berezina, N. P.
Sytcheva, A. A. -R.
JOURNAL OF MEMBRANE SCIENCE, 2008, 318 (1-2) : 255 - 263
[44] Evaluation of the Zn2+ transport properties through a cation-exchange membrane by chronopotentiometry
Herraiz-Cardona, I.
Ortega, E.
Perez-Herranz, V.
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2010, 341 (02) : 380 - 385
[45] Mathematical modeling of the transport characteristics of a PVDF-based cation-exchange membrane with low water content
Kislyi, A. G.
Kozmai, A. E.
Mareev, S. A.
Ponomar, M. A.
Anokhin, D. V.
Ivanov, D. A.
Umarov, A. Z.
Maryasevskaya, A. V.
Nikonenko, V. V.
JOURNAL OF MEMBRANE SCIENCE, 2024, 707
[46] Effect of Lactose on the Transport Properties of Ion-Exchange Membranes
Loza, N. V.
Kutenko, N. A.
Brovkina, M. A.
Samkov, A. A.
Kruglova, M. N.
MEMBRANES AND MEMBRANE TECHNOLOGIES, 2023, 5 (04) : 266 - 275
[47] Electrochemical Behavior of Polyaniline-Modified Cation-Exchange Heterogeneous Membranes in Solutions Containing Mono- and Bivalent Cations
M. A. Brovkina
N. A. Kutenko
N. V. Loza
Membranes and Membrane Technologies, 2023, 5 : 178 - 192
[48] The effect of the borate/boric acid buffer on the transfer of potassium counter-ion through a cation-exchange membrane: current-voltage characteristics
Zerdoumi, Ridha
Oulmi, Kafia
Bouhidel, Kamel-Eddine
DESALINATION AND WATER TREATMENT, 2013, 51 (31-33) : 6179 - 6183
[49] Copper cation transport and scaling of ionic exchange membranes using electrodialysis under electroconvection conditions
Chang, Jih-Hsing
Ellis, Amanda V.
Tung, Cheng-Hung
Huang, Wen-Chi
JOURNAL OF MEMBRANE SCIENCE, 2010, 361 (1-2) : 56 - 62
[50] Heterogenous bipolar membrane with amino methyl phosphonic acid functionalized cation exchange layer and montmorillonite nanoclay based interfacial layer
Eswaraswamy, Bhuvanesh
Mandal, Priyabrata
Goel, Priya
Suhag, Amit
Chattopadhyay, Sujay
CHEMICAL ENGINEERING JOURNAL ADVANCES, 2022, 12

← 1 2 3 4 5 →