Graphane and hydrogenated graphene

被引:288
作者
Pumera, Martin [1 ]
Wong, Colin Hong An [1 ]
机构
[1] Nanyang Technol Univ, Sch Phys & Math Sci, Div Chem & Biol Chem, Singapore 637371, Singapore
关键词
REVERSIBLE HYDROGENATION; FUNCTIONALIZATION; REDUCTION; METALS;
D O I
10.1039/c3cs60132c
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Graphane, the fully hydrogenated analogue of graphene, and its partially hydrogenated counterparts are attracting increasing attention. We review here its structure and predicted material properties, as well as the current methods of preparation. Graphane and hydrogenated graphenes are far more complex materials than graphene, expected to have a tuneable band gap via the extent of hydrogenation, as well as exhibit ferromagnetism. The methods for hydrogenated graphene characterization are discussed. We show that hydrogenation methods based on low or high pressure gas hydrogenation lead to less hydrogen saturation than wet chemistry methods based on variations of Birch reduction. The special cases of patterning of hydrogenated graphene strips in a graphene lattice are discussed.
引用
收藏
页码:5987 / 5995
页数:9
相关论文
共 48 条
[1]   Magnetic properties of hydrogenated bilayer graphene flakes [J].
Berashevich, J. ;
Chakraborty, T. .
EPL, 2011, 93 (04)
[2]   Reduction by dissolving metals. Part I. [J].
Birch, AJ .
JOURNAL OF THE CHEMICAL SOCIETY, 1944, :430-436
[3]   Hydrogen on graphene: Electronic structure, total energy, structural distortions and magnetism from first-principles calculations [J].
Boukhvalov, D. W. ;
Katsnelson, M. I. ;
Lichtenstein, A. I. .
PHYSICAL REVIEW B, 2008, 77 (03)
[4]   Tuning the gap in bilayer graphene using chemical functionalization: Density functional calculations [J].
Boukhvalov, D. W. ;
Katsnelson, M. I. .
PHYSICAL REVIEW B, 2008, 78 (08)
[5]   Tuning the electronic properties of graphene by hydrogenation in a plasma enhanced chemical vapor deposition reactor [J].
Burgess, James S. ;
Matis, Bernard R. ;
Robinson, Jeremy T. ;
Bulat, Felipe A. ;
Perkins, F. Keith ;
Houston, Brian H. ;
Baldwin, Jeffrey W. .
CARBON, 2011, 49 (13) :4420-4426
[6]  
Cancado L. G., 2006, APPL PHYS LETT, V88
[7]   Graphene Oxide: Preparation, Functionalization, and Electrochemical Applications [J].
Chen, Da ;
Feng, Hongbin ;
Li, Jinghong .
CHEMICAL REVIEWS, 2012, 112 (11) :6027-6053
[8]   Improved Stability and Catalytic Properties of Au16 Cluster Supported on Graphane [J].
Chen, G. ;
Li, S. J. ;
Su, Y. ;
Wang, V. ;
Mizuseki, H. ;
Kawazoe, Y. .
JOURNAL OF PHYSICAL CHEMISTRY C, 2011, 115 (41) :20168-20174
[9]   Transition-Metal-Atom-Embedded Graphane and Its Spintronic Device Applications [J].
Da, Haixia ;
Feng, Yuan Ping ;
Liang, Gengchaiu .
JOURNAL OF PHYSICAL CHEMISTRY C, 2011, 115 (46) :22701-22706
[10]   Non-hexagonal-ring defects and structures induced by healing and strain in graphene and functionalized graphene [J].
da Silva-Araujo, Joice ;
Nascimento, A. J. M. ;
Chacham, Helio ;
Nunes, R. W. .
NANOTECHNOLOGY, 2013, 24 (03)