Lewis acid-catalyzed reductive etherification of carbonyl compounds with alkoxyhydrosilanes

被引:0
|
作者
Miura, K [1 ]
Ootsuka, K [1 ]
Suda, S [1 ]
Nishikori, H [1 ]
Hosomi, A [1 ]
机构
[1] Univ Tsukuba, Grad Sch Pure & Appl Sci, Dept Chem, Tsukuba, Ibaraki 3058571, Japan
关键词
Lewis acids; reductive etherifications; ethers; aldehydes; bifunctional silicon reagents;
D O I
暂无
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The TMSI-catalyzed reaction of aldehydes and ketones with alkoxydimethylsilanes gave unsymmetrical ethers in good to high yields. This reductive etherification is superior to the conventional method using two kinds of silicon reagents in terms of atom efficiency and ease of operation.
引用
收藏
页码:313 / 315
页数:3
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