Monothiolate ruthenium alkylidene complexes with tricyclic fluorinated N-heterocyclic carbene ligands

被引：4

作者：

Akmalov, Timur R. ^{[1
]}

Masoud, Salekh M. ^{[1
]}

Vorobyeva, Dania V. ^{[1
]}

Dolgushin, Fedor M. ^{[1
]}

Nefedov, Sergey E. ^{[2
]}

Osipov, Sergey N. ^{[1
]}

机构：

[1] Russian Acad Sci, AN Nesmeyanov Inst Organoelement Cpds, Moscow 119991, Russia

[2] Russian Acad Sci, NS Kurnakov Inst Gen & Inorgan Chem, Moscow 119991, Russia

来源：

MENDELEEV COMMUNICATIONS | 2019年 / 29卷 / 01期

基金：

俄罗斯科学基金会;

关键词：

OLEFIN METATHESIS CATALYSTS;

D O I：

10.1016/j.mencom.2019.01.011

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

New monothiolate ruthenium alkylidene complexes bearing bulky tricyclic N-heterocyclic carbene ligands decorated with two geminal trifluoromethyl groups were synthesized. Their catalytic activity in representative olefin metathesis reactions, such as ring closing metathesis of diallyltosylamine and self-metathesis of allylbenzene, has been evaluated.

引用

页码：38 / 40

页数：3

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