Bis(1,4-diazoniabicyclo[2.2.2]octane) octamolybdate(VI) tetrahydrate

被引：11

作者：

Fang, RQ

Zhang, XM

Wu, HS

Ng, SW ^{[1
]}

机构：

[1] Shanxi Normal Univ, Sch Chem & Mat Sci, Linfen 041004, Peoples R China

[2] Univ Malaya, Dept Chem, Kuala Lumpur 50603, Malaysia

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2004年 / 60卷

关键词：

D O I：

10.1107/S1600536804004647

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The anionic entity in the title octamolybdate, (C6H14N2)(2)[Mo8O26].4H(2)O, has a chain structure in which the [Mo8O26](4-) units share terminal O atoms. The O atoms in the chain are two-, three- and four-coordinate. The anionic unit occupies a special position of (1) over bar site symmetry and the Mo-VI atoms are all octahedrally coordinated.

引用

页码：M359 / M361

页数：3

共 9 条

[1] CRYSTALLINE-STRUCTURE OF OCTAMOLYBDATE POLYMERS (NH4)5MO8O274H2O [J].

BOSCHEN, I ;

BUSS, B ;

KREBS, B .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1974, B 30 (JAN15) :48-56

[2]

*BRUK AXS INC, 2002, SADABS SAINT SMART

[3]

Farrugia L. J., 1999, J. Appl. Crystallogr, V32, P837, DOI DOI 10.1107/S0021889899006020

[4] CHAIN STRUCTURE OF POTASSIUM TETRAMOLYBDATE, K2MO4O13 [J].

GATEHOUS.BM ;

LEVERETT, P .

JOURNAL OF THE CHEMICAL SOCIETY D-CHEMICAL COMMUNICATIONS, 1970, (12) :740-&

[5]

Hagrman PJ, 1999, ANGEW CHEM INT EDIT, V38, P2639

[6]

Johnson C. K., 1976, ORNL5138

[7] Modeling hydroxyl and water H atoms [J].

Nardelli, M .

JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1999, 32 :563-571

[8]

Sheldrick G. M., 1997, SHELXS 97 PROGRAM CR

[9] Investigations into the engineering of inorganic organic solids: Hydrothermal synthesis and structure characterization of one-dimensional molybdenum oxide polymers [J].

Xu, Y ;

An, LH ;

Koh, LL .

CHEMISTRY OF MATERIALS, 1996, 8 (04) :814-818

← 1 →