Construction of a new 3D Zn(II) coordination polymer with (4,6)-connected topology: Synthesis, structure and luminescence

被引：2
作者：
Wang, Fu-min [1 ]
Liu, Jian-Qiang [2 ]
Jun, Wang [3 ]
Qin, Xiang-Yang [4 ]
机构：
[1] Weinan Normal Univ, Coll Chem & Life Sci, Shannxi, Peoples R China
[2] Guangdong Med Coll, Sch Pharm, Dongguan 523808, Peoples R China
[3] Sichuan Univ Sci & Engn, Sch Chem & Pharmaceut Engn, Zigong 643000, Peoples R China
[4] Fourth Mil Med Univ, Sch Pharm, Dept Chem, Xian 710032, Peoples R China
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2013年 / 35卷
基金：
中国国家自然科学基金;
关键词：
Luminescence; Topology; Co-ligand; METAL-ORGANIC FRAMEWORKS; CRYSTAL-STRUCTURE; POROUS FRAMEWORK; DESIGN; CHAINS; SERIES;
D O I：
10.1016/j.inoche.2013.06.022
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new coordination polymer of {[Zn-2(odPa)(IP)]]center dot 4H(2)O}(n) (1) (H(4)odpa = 3,3',4,4'-oxydiphthalic acid and IP = 1-H-imidazo[4,5-f][1,10]-phenanthroline), is reported. The 3D (4,6)-connected (4(4)center dot 6(2)center dot 8(8)center dot 12}{4(4)center dot 6(2)}) topology net is formed by IP and odpa ligands in I. Interestingly, the IP ligand acts as a tridentate mode and extends the resulting 3D feature. The luminescence study indicates that the title compound emits bright red fluorescence. (C) 2013 Elsevier B.V. All rights reserved.
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收藏
页码：169 / 171
页数：3
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