Crystal structure and optical properties of YMnO3 compound with high near-infrared reflectance

被引:54
作者
Han, Aijun [1 ]
Zhao, Minchun [1 ]
Ye, Mingquan [1 ]
Liao, Juanjuan [1 ]
Zhang, Zhimin [1 ]
Li, Nan [1 ]
机构
[1] Nanjing Univ Sci & Technol, Sch Chem Engn, Nanjing 210094, Jiangsu, Peoples R China
关键词
YMnO3; NIR reflectance; Sol gel; Cool pigments; THERMAL PERFORMANCE; COATINGS; BUILDINGS; PIGMENTS;
D O I
10.1016/j.solener.2013.01.011
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
The new application of YMnO3 as a high near-infrared (NIR) reflective inorganic pigment has been developed. Single-phased perovskite nanocrystalline YMnO3 samples with different average sizes have been synthesized through a polyacrylamide gel route. With the calcination temperature increasing from 700 degrees C to 900 degrees C, the color of the samples is blue-green, and the broad band value decreases from 1.89 to 1.58 eV due to the O-2p-Mn-3d charge-transfer transition. The NIR reflectance and solar reflectance values of corresponding pigmented coating increase from 51.4% to 53.4% and from 23.9% to 32.5%, respectively, which are higher than that of commercially available roofing products of the same color. The prepared YMnO3 pigment can be well served as colored "cool colorant". (C) 2013 Elsevier Ltd. All rights reserved.
引用
收藏
页码:32 / 36
页数:5
相关论文
共 24 条
[1]  
Bendiganavale Ashwini K., 2008, Recent Patents on Chemical Engineering, V1, P67
[2]   The synthesis, characterization and optical properties of silicon and praseodymium doped Y6MoO12 compounds: Environmentally benign inorganic pigments with high NIR reflectance [J].
George, Giable ;
Vishnu, V. S. ;
Reddy, M. L. P. .
DYES AND PIGMENTS, 2011, 88 (01) :109-115
[3]   Proposed reference irradiance spectra for solar energy systems testing [J].
Gueymard, CA ;
Myers, D ;
Emery, K .
SOLAR ENERGY, 2002, 73 (06) :443-467
[4]   Electronic structure of hexagonal rare-earth manganites RMnO3 [J].
Kalashnikova, AM ;
Pisarev, RV .
JETP LETTERS, 2003, 78 (03) :143-147
[5]   Development and testing of thermochromic coatings for buildings and urban structures [J].
Karlessi, T. ;
Santamouris, M. ;
Apostolakis, K. ;
Synnefa, A. ;
Livada, I. .
SOLAR ENERGY, 2009, 83 (04) :538-551
[6]   Solar spectral optical properties of pigments - Part I: model for deriving scattering and absorption coefficients from transmittance and reflectance measurements [J].
Levinson, R ;
Berdahl, P ;
Akbari, H .
SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2005, 89 (04) :319-349
[7]   Solar spectral optical properties of pigments - Part II: survey of common colorants [J].
Levinson, R ;
Berdahl, P ;
Akbari, H .
SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2005, 89 (04) :351-389
[8]   Inclusion of cool roofs in nonresidential Title 24 prescriptive requirements [J].
Levinson, R ;
Akbari, H ;
Konopacki, S ;
Bretz, S .
ENERGY POLICY, 2005, 33 (02) :151-170
[9]   Cooler tile-roofed buildings with near-infrared-reflective non-white coatings [J].
Levinson, Ronnen ;
Akbari, Hashem ;
Reilly, Joseph C. .
BUILDING AND ENVIRONMENT, 2007, 42 (07) :2591-2605
[10]   A novel technique for the production of cool colored concrete tile and asphalt shingle roofing products [J].
Levinson, Ronnen ;
Akbari, Hashem ;
Berdahl, Paul ;
Wood, Kurt ;
Skilton, Wayne ;
Petersheim, Jerry .
SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2010, 94 (06) :946-954