Sodium isopropyl xanthate degradation by advanced oxidation processes

被引:66
作者
Cifuentes Molina, Gerardo [1 ]
Herrera Cayo, Carmen [1 ,3 ]
Siqueira Rodrigues, Marco Antonio [2 ]
Bernardes, Andrea Moura [3 ]
机构
[1] Univ Santiago Chile, Fac Ingn, Dept Ing, Estn Cent, Santiago, Chile
[2] ICET, Ctr Univ Feevale, BR-93352000 Novo Hamburg, RS, Brazil
[3] Univ Fed Rio Grande do Sul, PPGE3M, BR-91501970 Porto Alegre, RS, Brazil
关键词
Sodium isopropyl xanthate; Advanced oxidation process; Copper mineral flotation; UV photolysis; Electrolysis; Photoelectrooxidation; INORGANIC-COMPOUNDS; RATE CONSTANTS; WASTE-WATER; OZONE; REAGENTS; REUSE; ACID;
D O I
10.1016/j.mineng.2012.12.001
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
This paper presents the results obtained by different oxidative processes when an aqueous solution containing sodium isopropyl xanthate is treated; this reagent is used in the flotation of copper minerals. The advanced oxidation processes used are UV photolysis, direct electrolysis and photoelectrooxidation. The solutions used containing sodium isopropyl xanthate were adjusted to the following concentrations: 6, 8, 10, 25 and 40 mg L-1. The results show that the three oxidation processes proved to be suitable for the destruction of xanthate, with the following maximum destruction efficiencies: 76% for electrolysis, 95% for UV photolysis and 99% for photoelectrooxidation. (C) 2012 Elsevier Ltd. All rights reserved.
引用
收藏
页码:88 / 93
页数:6
相关论文
共 29 条
[11]   Photocatalytic reduction of chromium and oxidation of organics by polyoxometalates [J].
Gkika, E ;
Troupis, A ;
Hiskia, A ;
Papaconstantinou, E .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2006, 62 (1-2) :28-34
[12]  
GLAZE WH, 1987, OZONE-SCI ENG, V9, P335
[13]  
HOIGNE J, 1983, WATER RES, V17, P185, DOI 10.1016/0043-1354(83)90099-4
[14]   RATE CONSTANTS OF REACTIONS OF OZONE WITH ORGANIC AND INORGANIC-COMPOUNDS IN WATER .1. NON-DISSOCIATING ORGANIC-COMPOUNDS [J].
HOIGNE, J ;
BADER, H .
WATER RESEARCH, 1983, 17 (02) :173-183
[15]   Treatment of combined acid mine drainage (AMD)-Flotation circuit effluents from copper mine via Fenton's process [J].
Mahiroglu, Ayse ;
Tarlan-Yel, Esra ;
Sevimli, Mehmet Faik .
JOURNAL OF HAZARDOUS MATERIALS, 2009, 166 (2-3) :782-787
[16]  
Oliveira Jr G.G., 2011, THESIS U FEDERAL MIN, P71
[17]   An overview of the use of chemical reagents in mineral processing [J].
Pearse, MJ .
MINERALS ENGINEERING, 2005, 18 (02) :139-149
[18]   Comparative study of commercial oxide electrodes performance in electrochemical degradation of organics in aqueous solutions [J].
Pelegrino, RL ;
Di Iglia, RA ;
Sanches, CG ;
Avaca, LA ;
Bertazzoli, R .
JOURNAL OF THE BRAZILIAN CHEMICAL SOCIETY, 2002, 13 (01) :60-65
[19]   Photoelectrochemical degradation of humic acid on a (TiO2)0.7(RuO2)0.3 dimensionally stable anode [J].
Pinhedo, L ;
Pelegrini, R ;
Bertazzoli, R ;
Motheo, AJ .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2005, 57 (02) :75-81
[20]   A REVIEW OF WATER RE-USE IN FLOTATION [J].
RAO, SR ;
FINCH, JA .
MINERALS ENGINEERING, 1989, 2 (01) :65-85